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• W1978360939 endingPage "11316" @default.
• W1978360939 startingPage "11310" @default.
• W1978360939 abstract "It is well-known that surface tension and surface energy are distinct quantities for solids. Each can be regarded as a thermodynamic property related first by Shuttleworth. Mullins and others have suggested that the difference between surface tension and surface energy cannot be sustained and that the two will approach each other over time. In this work we show that in a single-component system where changes in elastic energy can be neglected, the chemical potential difference between the surface and bulk is proportional to the difference between surface tension and surface energy. By further assuming that mass transfer is driven by this chemical potential difference, we establish a model for the kinetics by which mass transfer removes the difference between surface tension and surface energy." @default.
• W1978360939 created "2016-06-24" @default.
• W1978360939 creator A5003116978 @default.
• W1978360939 creator A5009476002 @default.
• W1978360939 date "2013-08-26" @default.
• W1978360939 modified "2023-09-23" @default.
• W1978360939 title "Surface Tension, Surface Energy, and Chemical Potential Due to Their Difference" @default.
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• W1978360939 doi "https://doi.org/10.1021/la400937r" @default.
• W1978360939 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23926928" @default.
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