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- W1978366245 abstract "ABSTRACT Novel rod–coil–rod ABA triblock copolymers, poly(3‐hexylthiophene)‐ block ‐poly(ethylene)‐ block ‐poly(3‐hexylthiophene) (P3HT‐ b ‐PE‐ b ‐P3HT) were synthesized by using a combination of a Ru‐catalyzed ring‐opening metathesis polymerization of 1,4‐cyclooctadiene in the presence of a suitable chain transfer agent (CTA) and a Ni‐catalyzed Grignard metathesis polymerization of 5‐chloromagnesio‐2‐bromo‐3‐hexylthiophene followed by hydrogenation. Using this methodology, the molecular weights of the poly(butadiene) (PBD) or the P3HT blocks were controlled by adjusting the initial monomer/CTA or the initial monomer/macroinitiator ratio, respectively. In addition, the triblock structure was confirmed by selective oxidative degradation of the PBD block found in the intermediate P3HT‐ b ‐PBD‐ b ‐P3HT copolymer produced in the aforementioned method, followed by analysis of the degradation products. Thermal analysis and atomic force microscopy of P3HT‐ b ‐PE‐ b ‐P3HT revealed that the material underwent phase separation in the solid state, a feature which may prove useful for improving charge mobilities within electronic devices. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51 , 3810–3817" @default.
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- W1978366245 date "2013-06-22" @default.
- W1978366245 modified "2023-10-16" @default.
- W1978366245 title "Synthesis of poly(3‐hexylthiophene)‐<i>block</i>‐poly(ethylene)‐<i>block</i>‐poly(3‐hexylthiophene) via a combination of ring‐opening olefin metathesis polymerization and grignard metathesis polymerization" @default.
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- W1978366245 doi "https://doi.org/10.1002/pola.26798" @default.
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