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• W1978374489 abstract "Von Tetraphenylcyclopentadien (1) und (4-tert-Butylphenyl)tetraphenylcyclopentadien (11) wurden die Alkalimetallsalze (2–4 bzw. 12, 13) und die luftstabilen Metallocene von Germanium (5, 15), Zinn (6, 16) und Blei (7, 17) synthetisiert und durch IR-, Raman-, 1H-NMR, 13C-NMR und Massenspektren sowie durch Röntgenpulverdiagramme charakterisiert. Vergleichende 13C-NMR-Studien unter Einbeziehung von Tetraphenylcyclopentadienylbromid (8), (4-tert-Butylphenyl)tetraphenylcyclopentadienol (9) und (4-tert-Butylphenyl)tetraphenylcyclopentadienylbromid (10) beweisen eine Delokalisierung der negativen Ladung des C5-Ringes in die nicht parallel angeordneten Phenylgruppen. Tetraphenylcyclopentadiene and (4-tert-Butylphenyl)tetraphenyl-cyclopentadiene: Synthesis and Characterization of their Alkali-Metal Salts and Metallocenes of Germanium, Tin, and Lead Tetraphenylcyclopentadiene (1) and (4-tert-butylphenyl)tetraphenylcyclopentadiene (11), their alkali-metal salts (2–4 and 12, 13, respectively) and their air-stable metallocenes of germanium (5, 15), tin (6, 16) and lead (7, 17) were synthesized and characterized by IR, Raman, 1H-NMR, 13C-NMR, and mass spectra as well as by X-ray powder diagrams. Comparative 13C-NMR studies including tetraphenylcyclopentadienyl bromide (8), (4-tert-butylphenyl)tetraphenylcyclopentadienol (9), and (4-tert-butylphenyl)tetraphenylcyclopentadienyl bromide (10) prove a delocalisation of the negative charge from the C5 ring into the nonparallel phenyl ligands." @default.
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• W1978374489 date "1988-02-01" @default.
• W1978374489 modified "2023-10-17" @default.
• W1978374489 title "Tetraphenylcyclopentadien und (4‐ <i>tert</i> ‐Butylphenyl)tetraphenylcyclopentadien: Synthese und Charakterisierung ihrer Alkalimetallsalze und Metallocene von Germanium, Zinn und Blei" @default.
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• W1978374489 doi "https://doi.org/10.1002/cber.19881210203" @default.
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