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- W1978380161 abstract "EPR investigations of the cr3+ ion in trigonal double molybdate RbIn(MoO4)2 are reported. The spin Hamiltonian parameters of the Cr3+ complexes are: g∥ = 1.9640, g| = 1.9680, |D| = = 0.5400 cm−1 at room temperature. Two structural phase transitions are observed by changes in the EPR spectra of the Cr3+ ion. The spin Hamiltonian parameters of the Cr3+ complexes in the ferroelastic phase are reported. A structural distortion model of the high-temperature phase is suggested. This model is based on the motion of the oxygen atoms of the anion (MoO4)2-, constituting the environment of In3+. Below T1 = 163 K the distortion leads to a monoclinic phase with the space group symmetry C2/c. [Russian Text Ignored]." @default.
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- W1978380161 date "1984-03-16" @default.
- W1978380161 modified "2023-09-27" @default.
- W1978380161 title "Phase transitions in ferroelastic RbIn(MoO4)2 crystals by electron paramagnetic resonance of Cr3+ ions" @default.
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- W1978380161 doi "https://doi.org/10.1002/pssa.2210820108" @default.
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