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- W1978390988 abstract "A series of perovskite phases have been prepared from the appropriate carbonates and oxides by heating under reducing conditions at temperatures up to 1300 °C. Complete ordering between ErO6 and MoO6 octahedra and a disordered distribution of Sr2+ and Ba2+ occur in all compounds. Neutron powder diffraction experiments show that the substitution of Sr2+ into Ba2ErMoO6 introduces a progressive reduction in symmetry from Fm3¯m (x=0) to I4/m (x=0.5, 0.8) to P21/n (x=1.25, 1.75, 2.0). Magnetic susceptibility measurements indicate that all of these compounds show Curie–Weiss paramagnetism and that for x<1.25 this behaviour persists down to 2 K. The monoclinically distorted compounds show magnetic transitions at low temperature and neutron diffraction has confirmed the presence of long-range antiferromagnetic order below 2.5 and 4 K in Ba0.25Sr1.75ErMoO6 and Sr2ErMoO6, respectively. Ba0.75Sr1.25ErMoO6, Ba0.25Sr1.75ErMoO6 and Sr2ErMoO6 do not undergo structural distortion on cooling from room temperature." @default.
- W1978390988 created "2016-06-24" @default.
- W1978390988 creator A5076283326 @default.
- W1978390988 date "2007-02-01" @default.
- W1978390988 modified "2023-10-14" @default.
- W1978390988 title "Structural and magnetic study of the cation-ordered perovskites Ba2−xSrxErMoO6" @default.
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- W1978390988 doi "https://doi.org/10.1016/j.jssc.2006.11.007" @default.
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