FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978392923> ?p ?o ?g. }

• W1978392923 endingPage "9633" @default.
• W1978392923 startingPage "9633" @default.
• W1978392923 abstract "The new [{Co5C(CO)12}Au{Co(CO)4}]−, [1]−, cluster has been obtained from the reaction of [Co6C(CO)15]2− with two equivalents of [AuCl4]−. [1]− reacts with an excess of HBF4 resulting in the formation of [{Co5C(CO)12}2Au]−, [2]−. The new derivatives [Co5C(CO)12(AuPPh3)], 3, and [Co5C(CO)11(AuPPh3)3], 4, have been obtained by reacting [2]− with two and four equivalents of [Au(PPh3)Cl], respectively. All the new species have been structurally characterised by means of X-ray crystallography as their [NEt4][1], [NEt4][2], [NMe3(CH2Ph)][2], 3 and 4·thf·0.5C6H14 salts and solvates. [2]− may be viewed as a homoleptic Au(I) complex containing two [Co5C(CO)12]− clusters as ligands. Similarly, [1]− and 3 are heteroleptic Au(I) complexes containing one [Co5C(CO)12]− cluster ligand as well as [Co(CO)4]− or PPh3. Conversely, 4 contains the [Co5C(CO)11]3− cluster stabilized by three [AuPPh3]+ fragments. [1]− and [2]− have been investigated in solution by means of electrochemical and spectroelectrochemical methods, revealing a very rich redox propensity to form the closely related [1]n− (n = 1–3) and [2]n− (n = 0–3) species." @default.
• W1978392923 created "2016-06-24" @default.
• W1978392923 creator A5001024113 @default.
• W1978392923 creator A5020784918 @default.
• W1978392923 creator A5041531483 @default.
• W1978392923 creator A5055414445 @default.
• W1978392923 creator A5055852692 @default.
• W1978392923 creator A5058900667 @default.
• W1978392923 creator A5060769015 @default.
• W1978392923 creator A5078588344 @default.
• W1978392923 date "2014-01-01" @default.
• W1978392923 modified "2023-10-16" @default.
• W1978392923 title "Homoleptic and heteroleptic Au(i) complexes containing the new [Co5C(CO)12]− cluster as ligand" @default.
• W1978392923 cites W1514906193 @default.
• W1978392923 cites W1559291190 @default.
• W1978392923 cites W1896805284 @default.
• W1978392923 cites W1974808490 @default.
• W1978392923 cites W1975156277 @default.
• W1978392923 cites W1975969135 @default.
• W1978392923 cites W1976943238 @default.
• W1978392923 cites W1980486554 @default.
• W1978392923 cites W1981577669 @default.
• W1978392923 cites W1986432682 @default.
• W1978392923 cites W1988681845 @default.
• W1978392923 cites W1992450375 @default.
• W1978392923 cites W1993992000 @default.
• W1978392923 cites W1996434405 @default.
• W1978392923 cites W2003990948 @default.
• W1978392923 cites W2010638247 @default.
• W1978392923 cites W2011476886 @default.
• W1978392923 cites W2012782673 @default.
• W1978392923 cites W2013604584 @default.
• W1978392923 cites W2022806415 @default.
• W1978392923 cites W2027686308 @default.
• W1978392923 cites W2030841140 @default.
• W1978392923 cites W2042300815 @default.
• W1978392923 cites W2046412723 @default.
• W1978392923 cites W2046723672 @default.
• W1978392923 cites W2050265893 @default.
• W1978392923 cites W2055292637 @default.
• W1978392923 cites W2056952278 @default.
• W1978392923 cites W2064843173 @default.
• W1978392923 cites W2068617439 @default.
• W1978392923 cites W2071882049 @default.
• W1978392923 cites W2073537128 @default.
• W1978392923 cites W2074589905 @default.
• W1978392923 cites W2075838216 @default.
• W1978392923 cites W2077490493 @default.
• W1978392923 cites W2079363233 @default.
• W1978392923 cites W2089015432 @default.
• W1978392923 cites W2092433033 @default.
• W1978392923 cites W2120901082 @default.
• W1978392923 cites W2121237359 @default.
• W1978392923 cites W2121690406 @default.
• W1978392923 cites W2128863855 @default.
• W1978392923 cites W213791877 @default.
• W1978392923 cites W2145023309 @default.
• W1978392923 cites W2149303217 @default.
• W1978392923 cites W2156257115 @default.
• W1978392923 cites W2162335578 @default.
• W1978392923 cites W2164144815 @default.
• W1978392923 cites W2315547281 @default.
• W1978392923 cites W2317807104 @default.
• W1978392923 cites W2321866205 @default.
• W1978392923 cites W2324385090 @default.
• W1978392923 cites W2325221925 @default.
• W1978392923 cites W2329476913 @default.
• W1978392923 cites W2331890660 @default.
• W1978392923 cites W2949694676 @default.
• W1978392923 cites W2952728432 @default.
• W1978392923 cites W3005417080 @default.
• W1978392923 cites W4239449886 @default.
• W1978392923 doi "https://doi.org/10.1039/c4dt00854e" @default.
• W1978392923 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24832236" @default.
• W1978392923 hasPublicationYear "2014" @default.
• W1978392923 type Work @default.
• W1978392923 sameAs 1978392923 @default.
• W1978392923 citedByCount "18" @default.
• W1978392923 countsByYear W19783929232014 @default.
• W1978392923 countsByYear W19783929232015 @default.
• W1978392923 countsByYear W19783929232017 @default.
• W1978392923 countsByYear W19783929232018 @default.
• W1978392923 countsByYear W19783929232019 @default.
• W1978392923 countsByYear W19783929232020 @default.
• W1978392923 countsByYear W19783929232021 @default.
• W1978392923 countsByYear W19783929232022 @default.
• W1978392923 countsByYear W19783929232023 @default.
• W1978392923 crossrefType "journal-article" @default.
• W1978392923 hasAuthorship W1978392923A5001024113 @default.
• W1978392923 hasAuthorship W1978392923A5020784918 @default.
• W1978392923 hasAuthorship W1978392923A5041531483 @default.
• W1978392923 hasAuthorship W1978392923A5055414445 @default.
• W1978392923 hasAuthorship W1978392923A5055852692 @default.
• W1978392923 hasAuthorship W1978392923A5058900667 @default.
• W1978392923 hasAuthorship W1978392923A5060769015 @default.
• W1978392923 hasAuthorship W1978392923A5078588344 @default.
• W1978392923 hasConcept C116569031 @default.
• W1978392923 hasConcept C147789679 @default.

• next