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• W1978393787 abstract "Abstract A study has been made comparing the micellization behaviour of diblock copolymers polystyrene-b-poly(tert-butylstyrene) and sulphonated polystyrene-b-poly(tert-butylstyrene) in the polar, selective solvent, dimethylformamide. In this solvent, poly(tert-butylstyrene) is insoluble and forms the compact core surrounded by either the solvated unfunctionalized polystyrene or the sulphonated polystyrene. The aggregation behaviour in the dilute solution region was studied using static and dynamic light scattering. The results confirmed that the ion-containing polymers form micelles with much larger overall size despite their smaller aggregation number as compared to those of the nonionic polymer. This behaviour can be interpreted as arising from the repulsion effect of the ionic charges on the polymer sequences in the corona. Viscosity measurements are also performed to show the effect of the aggregate size on the rheological properties." @default.
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• W1978393787 date "1992-06-01" @default.
• W1978393787 modified "2023-09-26" @default.
• W1978393787 title "Scattering studies of the associating behaviour of ionomeric and nonionomeric micelles in a selective solvent" @default.
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• W1978393787 doi "https://doi.org/10.1080/10101329208054580" @default.
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