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- W19783944 abstract "Ferrisilicates, containing iron in both framework and extraframework positions were synthesised. Characterisation using MASNMR, ESR, TPDA, ESCA and SIMS gave results which were consistent with framework substitution. Alumino-silicates crystallised more rapidly than corresponding ferrisilicates and a secondary nucleation of silicalite was observed in the iron system at prolonged crystallisation times. Acid sites in ferrisilicates were weaker than those in aluminosilicates. Product distributions, in the methanol conversion, were intermediate between those for H-ZSM-5 and silicalite. Relatively more coke and C 10 aromatics were observed with ferrisilicates and with iron impregnated silicalite. In the Fischer-Tropsch synthesis ferrisilicates were less active than iron impregnated silicalite but activity was improved by hydrothermal treatment which dislodged framework iron." @default.
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- W19783944 date "1986-01-01" @default.
- W19783944 modified "2023-09-27" @default.
- W19783944 title "The Synthesis and Characterisation of Iron Silicate Molecular Sieves Sieves" @default.
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- W19783944 doi "https://doi.org/10.1016/s0167-2991(09)60866-1" @default.
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