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• W1978396511 abstract "Structure refinement of high-resolution X-ray powder diffraction data of the title compound gave the composition Li(1.865)CoP(2)O(7), which is also verified by the ICP measurement. Two Co sites exist in the structure: one is a CoO(5) square pyramid and the other is a CoO(6) octa-hedron. They share edges and are further inter-connected through P(2)O(7) groups, forming a three-dimensional framework, which exhibits different kinds of inter-secting tunnels containing Li cations and could be of great inter-est in Li ion battery chemistry. The structure also exhibits cation disorder with 13.5% Co residing at the lithium (Li1) site. Co seems to have an average oxidation state of 2.135, as obtained from the strutural stochiometry that closely supports the magnetic susceptibility findings." @default.
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• W1978396511 date "2011-09-30" @default.
• W1978396511 modified "2023-09-27" @default.
• W1978396511 title "Lithium cobalt(II) pyrophosphate, Li_1.86CoP₂O₇, from synchrotron X-ray powder data" @default.
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• W1978396511 doi "https://doi.org/10.1107/s1600536811038451" @default.
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