Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978397101> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W1978397101 endingPage "L172" @default.
- W1978397101 startingPage "L169" @default.
- W1978397101 abstract "We report the first laser-induced thermal desorption (LITD) studies of acetylene on Pd(111). LITD coupled with Fourier transform mass spectrometry (FTMS) probes the surface molecular composition. Our results show simultaneous formation of thiophene and benzene at 120 K after a 6 L dose of acetylene at 80 K on a Pd(111) surface with 0.06 ML of sulfur. Simultaneous formation implies that formation of the C4H4 intermediate is the slow step in the formation of both cyclic products. The relative amounts of thiophene and benzene observed with LITD/FTMS are comparable, while thermal desorption spectroscopy (TDS) yields integrated thiophene signals that are < 2% as intense as for benzene. This indicates that thiophene primarily decomposes upon heating. Low coverage (0.5 L) results confirm reports that the presence of sulfur enhances benzene production." @default.
- W1978397101 created "2016-06-24" @default.
- W1978397101 creator A5016701895 @default.
- W1978397101 creator A5024095722 @default.
- W1978397101 creator A5050079616 @default.
- W1978397101 creator A5066535996 @default.
- W1978397101 date "1993-12-01" @default.
- W1978397101 modified "2023-09-27" @default.
- W1978397101 title "Benzene and thiophene formation from acetylene on sulfided Pd(111) studied by LITD/FTMS" @default.
- W1978397101 cites W119848184 @default.
- W1978397101 cites W1970592664 @default.
- W1978397101 cites W1971091592 @default.
- W1978397101 cites W1973857767 @default.
- W1978397101 cites W1985889987 @default.
- W1978397101 cites W1992552386 @default.
- W1978397101 cites W2008681371 @default.
- W1978397101 cites W2015094275 @default.
- W1978397101 cites W2024609267 @default.
- W1978397101 cites W2026413388 @default.
- W1978397101 cites W2031906460 @default.
- W1978397101 cites W2052895193 @default.
- W1978397101 cites W2062696577 @default.
- W1978397101 cites W2079799546 @default.
- W1978397101 cites W2086872633 @default.
- W1978397101 cites W2093230271 @default.
- W1978397101 cites W2138713767 @default.
- W1978397101 doi "https://doi.org/10.1016/0039-6028(93)90069-v" @default.
- W1978397101 hasPublicationYear "1993" @default.
- W1978397101 type Work @default.
- W1978397101 sameAs 1978397101 @default.
- W1978397101 citedByCount "17" @default.
- W1978397101 crossrefType "journal-article" @default.
- W1978397101 hasAuthorship W1978397101A5016701895 @default.
- W1978397101 hasAuthorship W1978397101A5024095722 @default.
- W1978397101 hasAuthorship W1978397101A5050079616 @default.
- W1978397101 hasAuthorship W1978397101A5066535996 @default.
- W1978397101 hasConcept C113196181 @default.
- W1978397101 hasConcept C147789679 @default.
- W1978397101 hasConcept C150394285 @default.
- W1978397101 hasConcept C162356407 @default.
- W1978397101 hasConcept C162711632 @default.
- W1978397101 hasConcept C178790620 @default.
- W1978397101 hasConcept C179104552 @default.
- W1978397101 hasConcept C185592680 @default.
- W1978397101 hasConcept C2777517455 @default.
- W1978397101 hasConcept C2777691172 @default.
- W1978397101 hasConcept C2779953032 @default.
- W1978397101 hasConcept C2781059571 @default.
- W1978397101 hasConcept C43617362 @default.
- W1978397101 hasConcept C518881349 @default.
- W1978397101 hasConcept C75473681 @default.
- W1978397101 hasConceptScore W1978397101C113196181 @default.
- W1978397101 hasConceptScore W1978397101C147789679 @default.
- W1978397101 hasConceptScore W1978397101C150394285 @default.
- W1978397101 hasConceptScore W1978397101C162356407 @default.
- W1978397101 hasConceptScore W1978397101C162711632 @default.
- W1978397101 hasConceptScore W1978397101C178790620 @default.
- W1978397101 hasConceptScore W1978397101C179104552 @default.
- W1978397101 hasConceptScore W1978397101C185592680 @default.
- W1978397101 hasConceptScore W1978397101C2777517455 @default.
- W1978397101 hasConceptScore W1978397101C2777691172 @default.
- W1978397101 hasConceptScore W1978397101C2779953032 @default.
- W1978397101 hasConceptScore W1978397101C2781059571 @default.
- W1978397101 hasConceptScore W1978397101C43617362 @default.
- W1978397101 hasConceptScore W1978397101C518881349 @default.
- W1978397101 hasConceptScore W1978397101C75473681 @default.
- W1978397101 hasIssue "1" @default.
- W1978397101 hasLocation W19783971011 @default.
- W1978397101 hasOpenAccess W1978397101 @default.
- W1978397101 hasPrimaryLocation W19783971011 @default.
- W1978397101 hasRelatedWork W1970592664 @default.
- W1978397101 hasRelatedWork W1978397101 @default.
- W1978397101 hasRelatedWork W2002469529 @default.
- W1978397101 hasRelatedWork W2048774102 @default.
- W1978397101 hasRelatedWork W2055668512 @default.
- W1978397101 hasRelatedWork W2072784659 @default.
- W1978397101 hasRelatedWork W2073105855 @default.
- W1978397101 hasRelatedWork W2115089515 @default.
- W1978397101 hasRelatedWork W2953005102 @default.
- W1978397101 hasRelatedWork W4304959976 @default.
- W1978397101 hasVolume "298" @default.
- W1978397101 isParatext "false" @default.
- W1978397101 isRetracted "false" @default.
- W1978397101 magId "1978397101" @default.
- W1978397101 workType "article" @default.