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- W1978397510 abstract "A chromotropic ferrocenyl chalcone with two pyrenyl groups (Fc-dPyr) is prepared and spectroscopically characterized. The X-ray structure analysis shows that the two pyrenyl groups are almost parallel to each other with a torsion angle of 5.57° and adopt a dimeric mode with a distance of 3.776 Å between them, ready to form an excimer. The solvatochromic fluorescence spectra indicate that the emission maxima observed in hydrogen-bonding donor (HBD) solvents (CHCl3, EtOH and MeOH) exhibit a strictly linear relationship with the normalized ETN value, while those in a non-HBD solvent (CH3CN) do not. The molecular chemosensor activity of Fc-dPyr is highly selective toward Fe(III) ions over Fe(II) ions. The fluorescence emission intensity of Fc-dPyr steeply decreases in the presence of Fe(III) ions as an oxidant, but not in the presence of Fe(II) ions." @default.
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- W1978397510 date "2010-11-01" @default.
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- W1978397510 title "Chromotropic ferrocenyl chalcone with two pyrenyl groups: Solvatochromism and molecular chemosensor for Fe(III)/Fe(II) ions" @default.
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- W1978397510 doi "https://doi.org/10.1016/j.inoche.2010.07.032" @default.
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