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- W1978397643 abstract "Aus photochemisch erzeugten Lösungen von Pentacarbonyl(tetrahydrofuran)-chrom und -wolfram bilden sich mit Tetramethyldistiban 1, Tetraethyldistiban 2, Tetra-tertbutyldistiban 3 und Tetraphenyldistiban 4 einkernige Komplexe des Typs (OC)5MSbR2SbR2 (5; M = Cr, W; R = CH3, C2H5, C6H5) sowie zweikernige Komplexe (OC)5MSbR2SbR2M(CO)5 (6; M = Cr, W; R = t-C4H9, C6H5). Die chemischen und spektroskopischen Eigenschaften dieser Verbindungen werden diskutiert. Preparation and Spectroscopic Investigations of Mono- and Binuclear Metalcarbonyl Complexes of Tetraalkyldistibane and Tetraphenyldistibane Ligands The reactions of photochemically generated solutions of pentacarbonyl (tetrahydrofurane)chromium and -tungsten with tetramethyldistibane 1, tetraethyldistibane 2, tetra-tert-butyldistibane 3, and tetraphenyldistibane 4 yield mononuclear complexes (OC)5MSbR2SbR2 (5; M = Cr, W; R = CH3, C2H5, C6H5) and binuclear complexes (OC)5MSbR2SbR2M(CO)5 (6; M = Cr, W; R = t-C4H9, C6H5). The chemical and spectroscopic properties of these compounds are discussed." @default.
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- W1978397643 date "1979-07-01" @default.
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- W1978397643 title "Synthese und spektroskopische Untersuchungen ein- und zweikerniger Metallcarbonylkomplexe mit Tetraalkyl- und Tetraphenyldistiban-Liganden" @default.
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- W1978397643 doi "https://doi.org/10.1002/zaac.19794540124" @default.
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