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- W1978397769 abstract "2,7-Di- and 2- halo-9,9′: 9′,9″-terfluorenyls were treated with the Raney nickel catalyst to give 9,9′: 9′,9″-terfluorenyl isomers (mp 293 °C (dec) (I) and mp 257 °C (dec) (II)), fluorene (III), 9,9′-bifluorenyl (IV), halofluorene, and/or 1,2,3,4,4a,9a-hexahydrofluorene (V). The conformation around the C9–C9′–C9″ single bonds of these halo-9,9′: 9′,9″-terfluorenyls were concluded to be s-cis, s-cis, identical with those of the parent hydrocarbon I. These assignments were confirmed by hydrogenolyzing 9,9″-dideuterio-2,7-dihalo-9,9′ : 9′,9″-terfluorenyls. The chemical shifts of the 9- and 9″-methine protons in these haloterfluorenyls were explained in terms of the torsional conformations of the molecules." @default.
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- W1978397769 date "1975-09-01" @default.
- W1978397769 modified "2023-09-25" @default.
- W1978397769 title "Hydrogenolyses of Halo-9,9′: 9′,9″-terfluorenyls with the Raney Nickel Catalyst" @default.
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- W1978397769 doi "https://doi.org/10.1246/bcsj.48.2487" @default.
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