FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978404191> ?p ?o ?g. }

• W1978404191 endingPage "4178" @default.
• W1978404191 startingPage "4170" @default.
• W1978404191 abstract "A sterically bulky chelating phosphine, tBu2P−CH2−C(CF3)2OH (1), was shown to stabilize divalent tin and germanium compounds: M[−O−C(CF3)2CH2PtBu2]2 (6, M = Sn; 14, M = Ge). Oxidizing reagents, e.g., sulfur, pyridine-N-oxide, and 1-azidoadamantane, reacted with divalent tin 6 on the phosphorus ligands exclusively, preserving the divalent state of tin in the resultant compounds Sn[−O−C(CF3)2CH2P(S)tBu2]2 (7), Sn[−O−C(CF3)2CH2P(O)tBu2]2 (11) and Sn[−O−C(CF3)2CH2PtBu2],[−O−C(CF3)2CH2P(N3-Adamantyl)tBu2]2 (12). The divalent germanium compound 14 was found to be more prone to oxidation to the tetravalent state. For example, the reaction with 1-azidoadamantane gave tetravalent germanium compounds Ge[−O−C(CF3)2CH2P(−)tBu],[-O−C(CF3)2CH2P(N-)tBu2] (16) and [Adamantyl],[−O−C(CF3)2CH2P(N−)]Ge−O−Ge[−O−C(CF3)2CH2P(tBu)2(N−)],[Adamantyl] (17). A Ge−O−Ge bridge in 17 is very linear, with an angle Ge−O−Ge of 177.4(2)°. According to X-ray analyses the intramolecular M−P bond lengths are among the longest known for this kind of bonding: 3.228(4) Å for P−Sn in 12 and 2.7585(12) Å for P−Ge in 14. The divalent tin compounds 6 and 7 were found to be efficient catalysts for the formation of polyurethanes. The divalent germanium compound 14 was active in polyurethane formation, but it was an order of magnitude less active than corresponding tin analogue 6." @default.
• W1978404191 created "2016-06-24" @default.
• W1978404191 creator A5011529626 @default.
• W1978404191 creator A5032702306 @default.
• W1978404191 creator A5045184508 @default.
• W1978404191 date "2006-07-11" @default.
• W1978404191 modified "2023-09-24" @default.
• W1978404191 title "Divalent Germanium and Tin Compounds Stabilized by Sterically Bulky P^∧O, PO^∧O, PS^∧O, and PN^∧O Ligands: Synthesis and First Insights into Catalytic Application to Polyurethane Systems" @default.
• W1978404191 cites W1969357678 @default.
• W1978404191 cites W1970808531 @default.
• W1978404191 cites W1975904638 @default.
• W1978404191 cites W1977273789 @default.
• W1978404191 cites W1979515338 @default.
• W1978404191 cites W1996774460 @default.
• W1978404191 cites W1999486301 @default.
• W1978404191 cites W1999979641 @default.
• W1978404191 cites W2001392616 @default.
• W1978404191 cites W2009253119 @default.
• W1978404191 cites W2010999953 @default.
• W1978404191 cites W2015822131 @default.
• W1978404191 cites W2029019776 @default.
• W1978404191 cites W2038074465 @default.
• W1978404191 cites W2039965218 @default.
• W1978404191 cites W2040556487 @default.
• W1978404191 cites W2042174595 @default.
• W1978404191 cites W2042609297 @default.
• W1978404191 cites W2044846780 @default.
• W1978404191 cites W2044970986 @default.
• W1978404191 cites W2046350425 @default.
• W1978404191 cites W2051132971 @default.
• W1978404191 cites W2053113159 @default.
• W1978404191 cites W2053980317 @default.
• W1978404191 cites W2058734069 @default.
• W1978404191 cites W2059213774 @default.
• W1978404191 cites W2076182472 @default.
• W1978404191 cites W2078044496 @default.
• W1978404191 cites W2079721349 @default.
• W1978404191 cites W2081471434 @default.
• W1978404191 cites W2086192392 @default.
• W1978404191 cites W2094068045 @default.
• W1978404191 cites W2106915211 @default.
• W1978404191 cites W2112251884 @default.
• W1978404191 cites W2145790857 @default.
• W1978404191 cites W2150316958 @default.
• W1978404191 cites W2161609648 @default.
• W1978404191 cites W2166375476 @default.
• W1978404191 cites W2319695470 @default.
• W1978404191 cites W2951855700 @default.
• W1978404191 cites W3004673938 @default.
• W1978404191 cites W4238617785 @default.
• W1978404191 doi "https://doi.org/10.1021/om060355c" @default.
• W1978404191 hasPublicationYear "2006" @default.
• W1978404191 type Work @default.
• W1978404191 sameAs 1978404191 @default.
• W1978404191 citedByCount "30" @default.
• W1978404191 countsByYear W19784041912012 @default.
• W1978404191 countsByYear W19784041912013 @default.
• W1978404191 countsByYear W19784041912014 @default.
• W1978404191 countsByYear W19784041912015 @default.
• W1978404191 countsByYear W19784041912016 @default.
• W1978404191 countsByYear W19784041912018 @default.
• W1978404191 countsByYear W19784041912020 @default.
• W1978404191 countsByYear W19784041912021 @default.
• W1978404191 countsByYear W19784041912022 @default.
• W1978404191 countsByYear W19784041912023 @default.
• W1978404191 crossrefType "journal-article" @default.
• W1978404191 hasAuthorship W1978404191A5011529626 @default.
• W1978404191 hasAuthorship W1978404191A5032702306 @default.
• W1978404191 hasAuthorship W1978404191A5045184508 @default.
• W1978404191 hasConcept C138973236 @default.
• W1978404191 hasConcept C155647269 @default.
• W1978404191 hasConcept C178790620 @default.
• W1978404191 hasConcept C179104552 @default.
• W1978404191 hasConcept C185592680 @default.
• W1978404191 hasConcept C197404232 @default.
• W1978404191 hasConcept C201194858 @default.
• W1978404191 hasConcept C2781311116 @default.
• W1978404191 hasConcept C525849907 @default.
• W1978404191 hasConcept C544956773 @default.
• W1978404191 hasConcept C550623735 @default.
• W1978404191 hasConcept C71240020 @default.
• W1978404191 hasConcept C74884574 @default.
• W1978404191 hasConcept C75079739 @default.
• W1978404191 hasConcept C8010536 @default.
• W1978404191 hasConceptScore W1978404191C138973236 @default.
• W1978404191 hasConceptScore W1978404191C155647269 @default.
• W1978404191 hasConceptScore W1978404191C178790620 @default.
• W1978404191 hasConceptScore W1978404191C179104552 @default.
• W1978404191 hasConceptScore W1978404191C185592680 @default.
• W1978404191 hasConceptScore W1978404191C197404232 @default.
• W1978404191 hasConceptScore W1978404191C201194858 @default.
• W1978404191 hasConceptScore W1978404191C2781311116 @default.
• W1978404191 hasConceptScore W1978404191C525849907 @default.
• W1978404191 hasConceptScore W1978404191C544956773 @default.
• W1978404191 hasConceptScore W1978404191C550623735 @default.
• W1978404191 hasConceptScore W1978404191C71240020 @default.
• W1978404191 hasConceptScore W1978404191C74884574 @default.
• W1978404191 hasConceptScore W1978404191C75079739 @default.

• next