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- W1978404611 abstract "Heats of formation of alkanes and alkyl radicals, along with kinetic and spectroscopic data, are used to derive appropriate group parameters: two atom parameters related to intrinsic bond energies and three atom parameters related to van der Waals interactions. The decrease in bond dissociation energies along the series CH 3 H, CH 3 CH 2 H, (CH 3 ) 2 CHH, (CH 3 ) 3 CH is deduced to be mainly due to differences in intrinsic bond energies on rehybridization, with electron delocalization playing only a minor role." @default.
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- W1978404611 date "1991-08-01" @default.
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- W1978404611 title "Stabilization effects in alkanes and in primary secondary and tertiary alkyl radicals" @default.
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- W1978404611 doi "https://doi.org/10.1016/s0040-4020(01)82329-2" @default.
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