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- W1978408229 abstract "The room-temperature lattice parameters of a series of CeNb1−xVxO4 and NdNb1−xVxO4 compounds (0 ≤ x ≤ 1) have been measured. Substitution of vanadium for niobium in both CeNbO4 and NdNbO4 drives the structure from monoclinic (fergusonite type) to tetragonal (scheelite type) atx = 0.296 and 0.346, respectively. In both systems, there is an expansion of the long-axis dimension of the fergusonite structure asx increases, despite the fact that vanadium is a smaller ion than niobium. This leads to an anomalous variation of the unit cell volume with concentration. The composition dependence of the strain parameters, which are a measure of the relative distortion of the monoclinic lattice, is found to fit a Landau mean-field model, thus demonstrating a thermodynamic correspondence between composition and temperature." @default.
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- W1978408229 date "1985-08-01" @default.
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- W1978408229 title "Composition dependence of lattice parameters in ANb1−xVxO4 systems whereA = Ce, Nd" @default.
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- W1978408229 doi "https://doi.org/10.1016/0022-4596(85)90355-x" @default.
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