FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978458586> ?p ?o ?g. }

• W1978458586 endingPage "2015" @default.
• W1978458586 startingPage "2009" @default.
• W1978458586 abstract "New oxovanadium(V) complexes with internally functionalized oximes of the type VO{OPri}3−n{ONC(CH3)(Ar)}n] (where Ar = C4H3O-2, C4H3S-2 and C5H4N-2 and n = 1–3) have been prepared in quantitative yields by the reaction of VO(OPri)3 with the corresponding oximes in various stoichiometric ratios in refluxing anhydrous benzene. The products have been characterized by elemental analyses and spectroscopic (FT IR, 1H, 13C{1H} and 51V NMR) studies. FAB mass spectral analysis of [VO{OPri}{ONC(CH3)C4H3S}2] indicates the monomeric nature of the complex. 51V NMR values for these complexes suggest the formation of tetra-coordinate species in solution. However, the single crystal X-ray diffraction studies of [VO{ONC(CH3)(C4H3O-2)}3] and [VO{ONC(CH3)(C4H3S-2)}3] · 0.5C6H6 exhibit the presence of vanadium(V) atoms in a unique hepta-coordination state with distorted pentagonal bipyramidal geometry in the solid state. The oxo- atom occupies the axial position while the oximato ligands are bonded in a dihapto (η2-N,O) manner with the formation of three membered rings." @default.
• W1978458586 created "2016-06-24" @default.
• W1978458586 creator A5004855784 @default.
• W1978458586 creator A5015254107 @default.
• W1978458586 creator A5025242443 @default.
• W1978458586 creator A5070499008 @default.
• W1978458586 creator A5072425073 @default.
• W1978458586 creator A5085452573 @default.
• W1978458586 date "2007-04-01" @default.
• W1978458586 modified "2023-10-18" @default.
• W1978458586 title "Synthesis and characterization of some oxovanadium(V) complexes with internally functionalized oximes: Crystal and molecular structures of heptacoordinated [VO{ONC(CH3)(C4H3O-2)}3] and [VO{ONC(CH3)(C4H3S-2)}3]·0.5C6H6" @default.
• W1978458586 cites W1964062405 @default.
• W1978458586 cites W1967427603 @default.
• W1978458586 cites W1973994610 @default.
• W1978458586 cites W1979640773 @default.
• W1978458586 cites W1980518643 @default.
• W1978458586 cites W1986323140 @default.
• W1978458586 cites W1988762158 @default.
• W1978458586 cites W1989956576 @default.
• W1978458586 cites W1992722368 @default.
• W1978458586 cites W1995155488 @default.
• W1978458586 cites W1998873730 @default.
• W1978458586 cites W1999275777 @default.
• W1978458586 cites W1999973531 @default.
• W1978458586 cites W2004400745 @default.
• W1978458586 cites W2005484095 @default.
• W1978458586 cites W2005964830 @default.
• W1978458586 cites W2006058972 @default.
• W1978458586 cites W2007552144 @default.
• W1978458586 cites W2009593904 @default.
• W1978458586 cites W2013032844 @default.
• W1978458586 cites W2014338134 @default.
• W1978458586 cites W2017247711 @default.
• W1978458586 cites W2028489875 @default.
• W1978458586 cites W2030040371 @default.
• W1978458586 cites W2032851574 @default.
• W1978458586 cites W2036350893 @default.
• W1978458586 cites W2040933066 @default.
• W1978458586 cites W2041671246 @default.
• W1978458586 cites W2042923956 @default.
• W1978458586 cites W2050353508 @default.
• W1978458586 cites W2050509117 @default.
• W1978458586 cites W2058008323 @default.
• W1978458586 cites W2061350948 @default.
• W1978458586 cites W2063334178 @default.
• W1978458586 cites W2064433913 @default.
• W1978458586 cites W2064715024 @default.
• W1978458586 cites W2070263336 @default.
• W1978458586 cites W2071542527 @default.
• W1978458586 cites W2074023212 @default.
• W1978458586 cites W2074462873 @default.
• W1978458586 cites W2080330469 @default.
• W1978458586 cites W2081996571 @default.
• W1978458586 cites W2085222038 @default.
• W1978458586 cites W2087127447 @default.
• W1978458586 cites W2088924005 @default.
• W1978458586 cites W2089658580 @default.
• W1978458586 cites W2122717944 @default.
• W1978458586 cites W2126478645 @default.
• W1978458586 cites W2132802692 @default.
• W1978458586 cites W2136201352 @default.
• W1978458586 cites W2141145271 @default.
• W1978458586 cites W2148066840 @default.
• W1978458586 cites W2150829534 @default.
• W1978458586 cites W2158410628 @default.
• W1978458586 cites W2951494481 @default.
• W1978458586 cites W2952523967 @default.
• W1978458586 cites W324521222 @default.
• W1978458586 cites W340877871 @default.
• W1978458586 cites W4231130756 @default.
• W1978458586 cites W4245376792 @default.
• W1978458586 doi "https://doi.org/10.1016/j.ica.2006.10.017" @default.
• W1978458586 hasPublicationYear "2007" @default.
• W1978458586 type Work @default.
• W1978458586 sameAs 1978458586 @default.
• W1978458586 citedByCount "23" @default.
• W1978458586 countsByYear W19784585862012 @default.
• W1978458586 countsByYear W19784585862014 @default.
• W1978458586 countsByYear W19784585862017 @default.
• W1978458586 countsByYear W19784585862019 @default.
• W1978458586 countsByYear W19784585862021 @default.
• W1978458586 countsByYear W19784585862023 @default.
• W1978458586 crossrefType "journal-article" @default.
• W1978458586 hasAuthorship W1978458586A5004855784 @default.
• W1978458586 hasAuthorship W1978458586A5015254107 @default.
• W1978458586 hasAuthorship W1978458586A5025242443 @default.
• W1978458586 hasAuthorship W1978458586A5070499008 @default.
• W1978458586 hasAuthorship W1978458586A5072425073 @default.
• W1978458586 hasAuthorship W1978458586A5085452573 @default.
• W1978458586 hasConcept C103319777 @default.
• W1978458586 hasConcept C115624301 @default.
• W1978458586 hasConcept C144082473 @default.
• W1978458586 hasConcept C147789679 @default.
• W1978458586 hasConcept C158842870 @default.
• W1978458586 hasConcept C166940927 @default.
• W1978458586 hasConcept C178790620 @default.
• W1978458586 hasConcept C179104552 @default.
• W1978458586 hasConcept C185592680 @default.

• next