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• W1978474708 abstract "Abstract In this work, we investigated the epitaxial crystallization and its determinant factor in the blends of high density polyethylene (HDPE) and a low crystallizable propylene-ethylene random copolymer (PPR) during injection molding. For PPR dominated blend (blended with 30 wt.% HDPE), epitaxial growth of HDPE on the PPR crystals can be achieved, as demonstrated by two-dimensional wide-angle X-ray diffraction and small-angle X-ray scattering measurements, though the crystallization of PPR was far behind that of HDPE component under quiescent conditions. In-situ shear infrared experiments indicated that PPR crystallized in advance mainly due to larger crystallization window and flow-induced crystallization acceleration. As for the blend with 70 wt.% HDPE, however, one could not observe epitaxy. Shear-induced crystallization of HDPE hindered its epitaxial growth. Once the formation of shish-kebab of HDPE was activated, the epitaxial growth would be suppressed to a large extent." @default.
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• W1978474708 date "2011-07-01" @default.
• W1978474708 modified "2023-09-27" @default.
• W1978474708 title "Flow-induced epitaxial growth of high density polyethylene in its blends with low crystallizable polypropylene copolymer" @default.
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• W1978474708 doi "https://doi.org/10.1016/j.polymer.2011.06.016" @default.
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