Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978494098> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W1978494098 abstract "Abstract The oxidation of Fe(NO) 2 (CO) 2 by tetracyanoethylene (TCNE), by the nitrosonium ion (NO + ), or by electrolysis in polar solvents was studied by EPR spectroscopy. A number of long‐lived (τ 1/2 of the order of hours) free radicals were detected in the early stages of reaction, all having similar isotropic g ‐factors and 14,15 N hyperfine interactions. These have been identified as the mononuclear cations, Fe(NO) 2 (CO) 2−n St n + (St = solvent molecule). They slowly disappear and are replaced by persistent radicals (τ 1/2 of the order of days) that show equal isotropic hyperfine interactions with four‐, six‐ or eight‐nitrogen nuclei. Infrared and EPR spectroscopic data suggest that two of these species are trinuclear nitrosyl clusters, Fe 3 (NO) 2n (CO) ( n = 3, 4), in which the unpaired spin is localized on one iron nucleus, but which are fluxional on the EPR time‐scale. The third nitrosyl radical with four equivalent NO ligands is tentatively identified as a binuclear intermediate that may be a precursor of the trinuclear clusters." @default.
- W1978494098 created "2016-06-24" @default.
- W1978494098 creator A5008154599 @default.
- W1978494098 creator A5057469709 @default.
- W1978494098 creator A5064204355 @default.
- W1978494098 date "1995-12-01" @default.
- W1978494098 modified "2023-09-25" @default.
- W1978494098 title "EPR study of iron—nitrosyl clusters in the oxidation of Fe(NO)2(CO)2" @default.
- W1978494098 cites W1594705125 @default.
- W1978494098 cites W1832291055 @default.
- W1978494098 cites W1970020345 @default.
- W1978494098 cites W1975082320 @default.
- W1978494098 cites W1998984215 @default.
- W1978494098 cites W2008577967 @default.
- W1978494098 cites W2015002216 @default.
- W1978494098 cites W2019814232 @default.
- W1978494098 cites W2020836698 @default.
- W1978494098 cites W2024788692 @default.
- W1978494098 cites W2033733908 @default.
- W1978494098 cites W2036236051 @default.
- W1978494098 cites W2040650285 @default.
- W1978494098 cites W2042436496 @default.
- W1978494098 cites W2058350555 @default.
- W1978494098 cites W2060572918 @default.
- W1978494098 cites W2070755003 @default.
- W1978494098 cites W2072785177 @default.
- W1978494098 cites W2082999371 @default.
- W1978494098 cites W2093563974 @default.
- W1978494098 cites W2094938386 @default.
- W1978494098 cites W2135739977 @default.
- W1978494098 cites W2951622104 @default.
- W1978494098 cites W3004960774 @default.
- W1978494098 cites W4242229945 @default.
- W1978494098 cites W4294617579 @default.
- W1978494098 doi "https://doi.org/10.1002/mrc.1260331305" @default.
- W1978494098 hasPublicationYear "1995" @default.
- W1978494098 type Work @default.
- W1978494098 sameAs 1978494098 @default.
- W1978494098 citedByCount "8" @default.
- W1978494098 countsByYear W19784940982013 @default.
- W1978494098 countsByYear W19784940982014 @default.
- W1978494098 countsByYear W19784940982016 @default.
- W1978494098 crossrefType "journal-article" @default.
- W1978494098 hasAuthorship W1978494098A5008154599 @default.
- W1978494098 hasAuthorship W1978494098A5057469709 @default.
- W1978494098 hasAuthorship W1978494098A5064204355 @default.
- W1978494098 hasConcept C121332964 @default.
- W1978494098 hasConcept C131538251 @default.
- W1978494098 hasConcept C139066938 @default.
- W1978494098 hasConcept C178790620 @default.
- W1978494098 hasConcept C185592680 @default.
- W1978494098 hasConcept C186927785 @default.
- W1978494098 hasConcept C187961010 @default.
- W1978494098 hasConcept C2780471494 @default.
- W1978494098 hasConcept C46141821 @default.
- W1978494098 hasConcept C62520636 @default.
- W1978494098 hasConcept C75473681 @default.
- W1978494098 hasConcept C8010536 @default.
- W1978494098 hasConceptScore W1978494098C121332964 @default.
- W1978494098 hasConceptScore W1978494098C131538251 @default.
- W1978494098 hasConceptScore W1978494098C139066938 @default.
- W1978494098 hasConceptScore W1978494098C178790620 @default.
- W1978494098 hasConceptScore W1978494098C185592680 @default.
- W1978494098 hasConceptScore W1978494098C186927785 @default.
- W1978494098 hasConceptScore W1978494098C187961010 @default.
- W1978494098 hasConceptScore W1978494098C2780471494 @default.
- W1978494098 hasConceptScore W1978494098C46141821 @default.
- W1978494098 hasConceptScore W1978494098C62520636 @default.
- W1978494098 hasConceptScore W1978494098C75473681 @default.
- W1978494098 hasConceptScore W1978494098C8010536 @default.
- W1978494098 hasIssue "13" @default.
- W1978494098 hasLocation W19784940981 @default.
- W1978494098 hasOpenAccess W1978494098 @default.
- W1978494098 hasPrimaryLocation W19784940981 @default.
- W1978494098 hasRelatedWork W1005342412 @default.
- W1978494098 hasRelatedWork W1618869875 @default.
- W1978494098 hasRelatedWork W2030548898 @default.
- W1978494098 hasRelatedWork W2033949665 @default.
- W1978494098 hasRelatedWork W2034406201 @default.
- W1978494098 hasRelatedWork W2047625142 @default.
- W1978494098 hasRelatedWork W2084759244 @default.
- W1978494098 hasRelatedWork W2524055164 @default.
- W1978494098 hasRelatedWork W2555528704 @default.
- W1978494098 hasRelatedWork W2563367549 @default.
- W1978494098 hasVolume "33" @default.
- W1978494098 isParatext "false" @default.
- W1978494098 isRetracted "false" @default.
- W1978494098 magId "1978494098" @default.
- W1978494098 workType "article" @default.