Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978496693> ?p ?o ?g. }
- W1978496693 endingPage "4799" @default.
- W1978496693 startingPage "4790" @default.
- W1978496693 abstract "The technique of arrested relaxation infrared chemiluminescence has been utilized for the observation of emission from the polyatomic substitution products of fluorine atom reactions with ethylene, propene, vinyl chloride, and vinyl bromide. A new apparatus for performing such experiments is described. The entire apparatus, including the scanning Michelson interferometer used in obtaining the emission spectra, is cooled to liquid nitrogen temperatures or lower. The resulting improvement in signal to noise ratio allows emission spectra to be recorded down to frequencies as low as 720 cm−1. Analysis of the chemiluminescence data allows the determination of the partitioning of reaction energy over the product vibrational modes. The results indicate statistical partitioning occurs for the vinyl chloride and bromide reactions, while the ethylene and propene reactions exhibit nonstatistical partitioning. The difference in energy partitioning for these reactions is attributed to the existence of a potential energy barrier in the exit channel for the latter two reactions, while no such barrier exists for the former reactions." @default.
- W1978496693 created "2016-06-24" @default.
- W1978496693 creator A5037963393 @default.
- W1978496693 creator A5042218726 @default.
- W1978496693 creator A5058222763 @default.
- W1978496693 creator A5081804855 @default.
- W1978496693 date "1974-06-15" @default.
- W1978496693 modified "2023-10-10" @default.
- W1978496693 title "Infrared chemiluminescence studies of the reaction of fluorine atoms with monosubstituted ethylene compounds" @default.
- W1978496693 cites W1521493173 @default.
- W1978496693 cites W1571837143 @default.
- W1978496693 cites W1658777500 @default.
- W1978496693 cites W1965431807 @default.
- W1978496693 cites W1966727549 @default.
- W1978496693 cites W1973180722 @default.
- W1978496693 cites W1987741147 @default.
- W1978496693 cites W1988756867 @default.
- W1978496693 cites W1991137493 @default.
- W1978496693 cites W1994658556 @default.
- W1978496693 cites W2004397879 @default.
- W1978496693 cites W2006705506 @default.
- W1978496693 cites W2010394612 @default.
- W1978496693 cites W2016541558 @default.
- W1978496693 cites W2024268546 @default.
- W1978496693 cites W2031007777 @default.
- W1978496693 cites W2033372290 @default.
- W1978496693 cites W2036365670 @default.
- W1978496693 cites W2045754576 @default.
- W1978496693 cites W2052998923 @default.
- W1978496693 cites W2053304675 @default.
- W1978496693 cites W2055524517 @default.
- W1978496693 cites W2063004126 @default.
- W1978496693 cites W2064564447 @default.
- W1978496693 cites W2066934743 @default.
- W1978496693 cites W2069775221 @default.
- W1978496693 cites W2082364091 @default.
- W1978496693 cites W2093786393 @default.
- W1978496693 cites W2124779205 @default.
- W1978496693 cites W2127814611 @default.
- W1978496693 cites W2127847807 @default.
- W1978496693 cites W2142079741 @default.
- W1978496693 cites W2331524641 @default.
- W1978496693 cites W2335019639 @default.
- W1978496693 cites W3005223215 @default.
- W1978496693 cites W3022814030 @default.
- W1978496693 cites W4238952477 @default.
- W1978496693 doi "https://doi.org/10.1063/1.1680982" @default.
- W1978496693 hasPublicationYear "1974" @default.
- W1978496693 type Work @default.
- W1978496693 sameAs 1978496693 @default.
- W1978496693 citedByCount "95" @default.
- W1978496693 countsByYear W19784966932012 @default.
- W1978496693 countsByYear W19784966932015 @default.
- W1978496693 countsByYear W19784966932017 @default.
- W1978496693 countsByYear W19784966932020 @default.
- W1978496693 crossrefType "journal-article" @default.
- W1978496693 hasAuthorship W1978496693A5037963393 @default.
- W1978496693 hasAuthorship W1978496693A5042218726 @default.
- W1978496693 hasAuthorship W1978496693A5058222763 @default.
- W1978496693 hasAuthorship W1978496693A5081804855 @default.
- W1978496693 hasConcept C113196181 @default.
- W1978496693 hasConcept C120665830 @default.
- W1978496693 hasConcept C121332964 @default.
- W1978496693 hasConcept C145148216 @default.
- W1978496693 hasConcept C145802702 @default.
- W1978496693 hasConcept C147789679 @default.
- W1978496693 hasConcept C153642686 @default.
- W1978496693 hasConcept C158355884 @default.
- W1978496693 hasConcept C15920480 @default.
- W1978496693 hasConcept C161790260 @default.
- W1978496693 hasConcept C177801218 @default.
- W1978496693 hasConcept C178790620 @default.
- W1978496693 hasConcept C179104552 @default.
- W1978496693 hasConcept C185592680 @default.
- W1978496693 hasConcept C2776300020 @default.
- W1978496693 hasConcept C2777954637 @default.
- W1978496693 hasConcept C2778597550 @default.
- W1978496693 hasConcept C2779144480 @default.
- W1978496693 hasConcept C2781460079 @default.
- W1978496693 hasConcept C521977710 @default.
- W1978496693 hasConcept C66594872 @default.
- W1978496693 hasConcept C75473681 @default.
- W1978496693 hasConceptScore W1978496693C113196181 @default.
- W1978496693 hasConceptScore W1978496693C120665830 @default.
- W1978496693 hasConceptScore W1978496693C121332964 @default.
- W1978496693 hasConceptScore W1978496693C145148216 @default.
- W1978496693 hasConceptScore W1978496693C145802702 @default.
- W1978496693 hasConceptScore W1978496693C147789679 @default.
- W1978496693 hasConceptScore W1978496693C153642686 @default.
- W1978496693 hasConceptScore W1978496693C158355884 @default.
- W1978496693 hasConceptScore W1978496693C15920480 @default.
- W1978496693 hasConceptScore W1978496693C161790260 @default.
- W1978496693 hasConceptScore W1978496693C177801218 @default.
- W1978496693 hasConceptScore W1978496693C178790620 @default.
- W1978496693 hasConceptScore W1978496693C179104552 @default.
- W1978496693 hasConceptScore W1978496693C185592680 @default.
- W1978496693 hasConceptScore W1978496693C2776300020 @default.
- W1978496693 hasConceptScore W1978496693C2777954637 @default.