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• W1978499319 abstract "Abstract Novel supramolecular networks of 2D {[Ni(cyclam)][C 6 H 9 (COOH) 2 (COO)] 2 } n ( 1 ) and 3D {[Ni(cyclam)][C 6 H 3 (OH) 2 (COO)] 2 } n ( 2 ) have been constructed by the self‐assembly of [Ni(cyclam)](ClO 4 ) 2 with cis , cis ‐1,3,5‐cyclohexanetricarboxylic acid (H 3 CTC) and 3,5‐dihydroxybenzoic acid (HDHB), respectively, in py/MeCN/H 2 O. In the crystal structure of 1 , each nickel( II ) macrocyclic complex binds two H 2 CTC − ions at the axial sites. The coordinated H 2 CTC − ions form hydrogen bonds with one another, which results in organic bilayers having macrocyclic complexes as pillars. In the crystal structure of 2 , each nickel( II ) macrocyclic complex binds two DHB − ions in the trans position. Two free hydroxyl groups and one carbonyl oxygen atom of the coordinated DHB − ion are extensively hydrogen‐bonded with the DHB − ligand of the neighboring complexes, which results in a 3D network where 2D organic layers are linked by the macrocyclic complexes acting as pillars. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)" @default.
• W1978499319 created "2016-06-24" @default.
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• W1978499319 date "2003-03-24" @default.
• W1978499319 modified "2023-09-23" @default.
• W1978499319 title "Assembly of Hydrogen‐Bonded Organic Layers with Macrocyclic Complexes Acting as Pillars" @default.
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• W1978499319 doi "https://doi.org/10.1002/ejic.200390178" @default.
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