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- W1978500278 abstract "Isopiestic measurements have been made on SrCl2(aq) and BaCl2(aq) over the temperature range 382.96 to 473.61 K with NaCl(aq) as the reference solution for the calculation of osmotic coefficients. The molalities corresponded to NaCl(aq) molalities ranging from 0.6 to 6.5 mol kg−1. An ion-interaction model was fitted to the osmotic coefficients of SrCl2(aq) and BaCl2(aq) with a standard deviation of fit (in the osmotic coefficient) ranging from 0.0007 to 0.0048. Parameters derived from the fit were used to calculate the activity coefficients. The osmotic and activity coefficients decrease with increasing temperature and become less dependent on molality. Previous isopiestic results between 318 and 394 K agree with the present study. Activity coefficients from electrochemical measurements between 283.15 and 343.15 K are not consistent with the isopiestic results." @default.
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- W1978500278 date "1981-11-01" @default.
- W1978500278 modified "2023-10-14" @default.
- W1978500278 title "Isopiestic studies of aqueous solutions at elevated temperatures V. SrCl2 and BaCl2" @default.
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- W1978500278 doi "https://doi.org/10.1016/0021-9614(81)90002-1" @default.
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