Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978505512> ?p ?o ?g. }
- W1978505512 endingPage "893" @default.
- W1978505512 startingPage "885" @default.
- W1978505512 abstract "Chromium-replaced PbMoO4, PbMo1−xCrxO4, prepared by an aqueous reflux method, showed a photocatalytic activity for O2 evolution from an aqueous solution containing an electron accepter, such as Ag+ or Fe3+ under visible light irradiation (vis) (λ ≥ 420 nm). PbMo0.98Cr0.02O4 (Energy gap: 2.26 eV) showed the highest activity for the O2 evolution under vis and UV + vis light irradiation. The activity of PbMo0.98Cr0.02O4 was one order of magnitude higher than that of PbMoO4 under UV + vis light irradiation. The crystal structures of PbMo1−xCrxO4 were studied by the Rietveld analysis for powder X-ray diffraction. PbMo1−xCrxO4 had a scheelite-type structure when x was equal to or smaller than 0.2. The energy band structures of PbMo1−xCrxO4 were calculated based on density functional theory using the structural parameters refined by the Rietveld analysis. It was revealed that the top of the valence band of PbMoO4 consisted of O2p and Pb6s orbitals and the accepter level was composed of a Cr3d orbital in the forbidden band below the conduction band consisting of a Mo4d orbital. It was concluded that the visible light response was due to the excitation from the Pb6s + O2p valence band to the Cr3d accepter level." @default.
- W1978505512 created "2016-06-24" @default.
- W1978505512 creator A5009468369 @default.
- W1978505512 creator A5014036614 @default.
- W1978505512 creator A5017260854 @default.
- W1978505512 creator A5073855812 @default.
- W1978505512 date "2007-05-15" @default.
- W1978505512 modified "2023-10-12" @default.
- W1978505512 title "Investigations of Electronic Structures and Photocatalytic Activities under Visible Light Irradiation of Lead Molybdate Replaced with Chromium(VI)" @default.
- W1978505512 cites W1545479456 @default.
- W1978505512 cites W1965797302 @default.
- W1978505512 cites W1981368803 @default.
- W1978505512 cites W1982830588 @default.
- W1978505512 cites W1985810494 @default.
- W1978505512 cites W1986145408 @default.
- W1978505512 cites W1995753210 @default.
- W1978505512 cites W2005066391 @default.
- W1978505512 cites W2011187807 @default.
- W1978505512 cites W2012134384 @default.
- W1978505512 cites W2013243712 @default.
- W1978505512 cites W2023966769 @default.
- W1978505512 cites W2026385684 @default.
- W1978505512 cites W2027459972 @default.
- W1978505512 cites W2033737637 @default.
- W1978505512 cites W2035179036 @default.
- W1978505512 cites W2038131683 @default.
- W1978505512 cites W2038628080 @default.
- W1978505512 cites W2038869535 @default.
- W1978505512 cites W2040225364 @default.
- W1978505512 cites W2044865687 @default.
- W1978505512 cites W2046442571 @default.
- W1978505512 cites W2067232009 @default.
- W1978505512 cites W2072128348 @default.
- W1978505512 cites W2072512988 @default.
- W1978505512 cites W2075307778 @default.
- W1978505512 cites W2076614020 @default.
- W1978505512 cites W2080255921 @default.
- W1978505512 cites W2087585288 @default.
- W1978505512 cites W2089142154 @default.
- W1978505512 cites W2098432400 @default.
- W1978505512 cites W2103800014 @default.
- W1978505512 cites W2118323507 @default.
- W1978505512 cites W2124734280 @default.
- W1978505512 cites W2131816354 @default.
- W1978505512 cites W2143092464 @default.
- W1978505512 cites W2156416303 @default.
- W1978505512 cites W2167590372 @default.
- W1978505512 cites W2319640213 @default.
- W1978505512 cites W2525722724 @default.
- W1978505512 cites W2526793459 @default.
- W1978505512 cites W2949605747 @default.
- W1978505512 doi "https://doi.org/10.1246/bcsj.80.885" @default.
- W1978505512 hasPublicationYear "2007" @default.
- W1978505512 type Work @default.
- W1978505512 sameAs 1978505512 @default.
- W1978505512 citedByCount "66" @default.
- W1978505512 countsByYear W19785055122012 @default.
- W1978505512 countsByYear W19785055122013 @default.
- W1978505512 countsByYear W19785055122014 @default.
- W1978505512 countsByYear W19785055122015 @default.
- W1978505512 countsByYear W19785055122016 @default.
- W1978505512 countsByYear W19785055122017 @default.
- W1978505512 countsByYear W19785055122018 @default.
- W1978505512 countsByYear W19785055122019 @default.
- W1978505512 countsByYear W19785055122020 @default.
- W1978505512 countsByYear W19785055122021 @default.
- W1978505512 countsByYear W19785055122022 @default.
- W1978505512 countsByYear W19785055122023 @default.
- W1978505512 crossrefType "journal-article" @default.
- W1978505512 hasAuthorship W1978505512A5009468369 @default.
- W1978505512 hasAuthorship W1978505512A5014036614 @default.
- W1978505512 hasAuthorship W1978505512A5017260854 @default.
- W1978505512 hasAuthorship W1978505512A5073855812 @default.
- W1978505512 hasBestOaLocation W19785055121 @default.
- W1978505512 hasConcept C104663316 @default.
- W1978505512 hasConcept C111337013 @default.
- W1978505512 hasConcept C115624301 @default.
- W1978505512 hasConcept C115645028 @default.
- W1978505512 hasConcept C121332964 @default.
- W1978505512 hasConcept C147789679 @default.
- W1978505512 hasConcept C161790260 @default.
- W1978505512 hasConcept C168900304 @default.
- W1978505512 hasConcept C178790620 @default.
- W1978505512 hasConcept C181966813 @default.
- W1978505512 hasConcept C184651966 @default.
- W1978505512 hasConcept C185544564 @default.
- W1978505512 hasConcept C185592680 @default.
- W1978505512 hasConcept C192562407 @default.
- W1978505512 hasConcept C49040817 @default.
- W1978505512 hasConcept C65165184 @default.
- W1978505512 hasConcept C75473681 @default.
- W1978505512 hasConcept C8010536 @default.
- W1978505512 hasConceptScore W1978505512C104663316 @default.
- W1978505512 hasConceptScore W1978505512C111337013 @default.
- W1978505512 hasConceptScore W1978505512C115624301 @default.
- W1978505512 hasConceptScore W1978505512C115645028 @default.
- W1978505512 hasConceptScore W1978505512C121332964 @default.
- W1978505512 hasConceptScore W1978505512C147789679 @default.