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• W1978507466 startingPage "3492" @default.
• W1978507466 abstract "Characteristic ions (M+1)+ and (M+45)+, assigned to be the protonated monomer ion MH+ and (M·CO2H)+ respectively, have been detected in the mass spectrometric measurements of the dimer molecules M2 and the higher clusters Mn of some carboxylic acids produced in their nozzle beams. It has been shown from the dependences of their relative intensities on the stagnation conditions that these ions are mainly formed through the fragmentation of the dimer ions. The MH+ ion plays the most important role in these fragmentation processes of the dimers, while no dimer ion M2+ was observed. These results are discussed in terms of the enthalpy changes for the unimolecular decomposition reactions of M2+." @default.
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• W1978507466 date "1980-12-01" @default.
• W1978507466 modified "2023-09-26" @default.
• W1978507466 title "Mass Spectrometric Studies of Some Carboxylic Acid Dimers Produced by a Nozzle Beam: HCO₂H, CH₃CO₂H, C₂H₅CO₂H, and<i>n</i>-C₃H₇CO₂H" @default.
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• W1978507466 doi "https://doi.org/10.1246/bcsj.53.3492" @default.
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