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- W1978541898 abstract "Polymerization of methyl methacrylate (MMA) with a radical initiator covalently immobilized 4,4′-azobis(4-cyanopetanoyl) (ACP) group on the inside wall of MCM-41 (ACP-MCM-41) was investigated. The polymerization of MMA with ACP-MCM-41 proceeded to give high-molecular weight polymers. The relationship between the Mn of the resulting polymer and the polymer yield gave a straight line, and the line passed through the origin, which is in contrast to that such relationship was not observed in the polymerization of MMA with dimethyl 2,2′-azobis(2-methyl propionate) (MAIB) even in the cavity of MCM-41. The results demonstrates that the termination reactions of the propagating radicals were extremely suppressed by movement restriction of the polymer chains covalently immobilized on the inside wall of MCM-41 in the polymerization of MMA. The presence of super long-lived propagating radical on the inside wall of MCM-41 was confirmed by ESR measurement and post-polymerization." @default.
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- W1978541898 date "2009-01-01" @default.
- W1978541898 modified "2023-10-14" @default.
- W1978541898 title "Polymerization of Methyl Methacrylate with Radical Initiator Immobilized on the Inside Wall of Mesoporous Silica" @default.
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- W1978541898 doi "https://doi.org/10.1295/polymj.pj2008332" @default.
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