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- W1978543624 abstract "The proton nuclear spin-lattice relaxation rate 1/T1 in the molecular ferric wheel Fe10(OCH3)20(C2H2O2Cl)10 (Fe10) is calculated in the framework of the linear response theory, starting from the unperturbed eigenvalues and eigenstates of the magnetic ring. The dipole-dipole superhyperfine interaction between the proton nuclear spins and the electronic spins of the magnetic ions is shown to induce transitions between states |S,M which differ by 1 both in the quantum number S (the total spin of the ring) and in M (the projection of the total spin along the quantization axis). The theory predicts that level crossing between the states |S + 1, − (S + 1) and |S, − S induced by an applied magnetic field should be accompanied by a strong enhancement of T1−1, in good agreement with recent low-temperature NMR experimental data on Fe10." @default.
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- W1978543624 date "2000-04-01" @default.
- W1978543624 modified "2023-09-27" @default.
- W1978543624 title "Low-temperature theory of proton NMR in the molecular antiferromagnetic ring Fe10" @default.
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- W1978543624 doi "https://doi.org/10.1209/epl/i2000-00239-3" @default.
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