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• W1978544065 abstract "The O-exchange reaction between CO2+ and CO is triggered by two different entrance channels in 13C-labeled systems. The unimolecular dissociation of the C13CO3(+) reactive intermediate is investigated at varying energies by mass spectrometric techniques. An almost one-way O-exchange at energies close to the dissociation threshold discloses a remarkably large intramolecular 12C/13C kinetic isotope effect ranging from 6.0 to 7.3 +/- 0.5." @default.
• W1978544065 created "2016-06-24" @default.
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• W1978544065 date "2008-03-01" @default.
• W1978544065 modified "2023-09-23" @default.
• W1978544065 title "Isotope Effects in Isotope-Exchange Reactions: Evidence for a Large ¹²C/¹³C Kinetic Isotope Effect in the Gas Phase" @default.
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• W1978544065 doi "https://doi.org/10.1021/jp710634p" @default.
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