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- W1978551168 abstract "Abstract A variable temperature 300 MHz NMR investigation of trans-10-bromo-10,11-dihydro-11-hydroxy-5H-dibenz[b,f]azepine-5-carbonyl chloride has shown the presence of two conformationally restricted isomers, both bearing antioriented a protons and hydrogen bonded gauche substituents at C(10) and C(11), which are interconverted through‘ ring inversion by torsion about the C(4a)-N(5)-C(5a) bonds. The free energy of activation for the ring inversion process, obtained in the 21-38°C temperature range, is ΔG 1 T = 16.5±0.2 Kcal mol-1" @default.
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- W1978551168 date "1988-01-01" @default.
- W1978551168 modified "2023-09-26" @default.
- W1978551168 title "Restricted conformational processes in 10,11-dihydro-5h-dibenz [b,f]azepine erivatives. a DNMR study" @default.
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- W1978551168 doi "https://doi.org/10.1016/s0040-4020(01)86190-1" @default.
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