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- W1978561211 abstract "The preparation of Ag-X and Ag,Ca-X zeolites, and their properties as catalysts for the oxidation of cyclohexene by air, were studied. The catalysts were prepared by ion-exchange of zeolite 13X, and subsequent reduction with hydrogen. The oxidation of cyclohexene was performed in a tubular reactor, at 270 °C and atmospheric pressure and the conversion was 6–8%. The products obtained, identified by gas chromatography and infrared spectroscopy, were cyclohexene oxide, 2-cyclohexene-1-one, 1-cyclopentene-1-carboxaldehyde, and 1,6-hexanedial. Only traces of CO2 (0.2%) were detected. The selectivity of the catalysts was affected by altering the calcium content; thus, Ag-X showed rather high selectivity for the epoxide, while in the presence of Ca the main product was 1-cyclopentene-1-carboxaldehyde." @default.
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- W1978561211 date "1984-06-01" @default.
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- W1978561211 title "Silver supported on zeolite as catalyst for the oxidation of olefins" @default.
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- W1978561211 doi "https://doi.org/10.1016/0021-9517(84)90192-1" @default.
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