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• W1978573265 abstract "Total synthesis of the unnatural enantiomer of deacetylravidomycin M was accomplished. The key steps include, (1) aryl C-glycosidation of the azido-bearing fucosyl acetate 2 by using catalytic Sc(OTf)3, (2) the [2+2] cycloaddition reaction of alkoxybenzyne bearing an azido sugar to ketene silyl acetal, and (3) the ring expansion reaction of alkoxybenzocyclobutenone. The synthesis revealed that the natural product is not the proposed amine, but the corresponding N-oxide." @default.
• W1978573265 created "2016-06-24" @default.
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• W1978573265 date "2011-09-01" @default.
• W1978573265 modified "2023-09-27" @default.
• W1978573265 title "Total synthesis and structure revision of deacetylravidomycin M" @default.
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• W1978573265 doi "https://doi.org/10.1016/j.tet.2011.06.046" @default.
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