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• W1978577159 abstract "Abstract Fast chiral separation of DNS‐amino acids could be realized using microchip electrophoresis with fluorescence detection. For this purpose, highly sulfated cyclodextrins (HS‐γ‐CD) were used as chiral selectors enabling high selectivity. Even subsecond separation of DNS‐tryptophan, DNS‐norleucine, DNS‐phenylalanine, DNS‐methionine, and DNS‐aspartic acid could be achieved. Baseline separation could be accomplished within 720 ms, which is the fastest separation of enantiomers reported to date. A more complex mixture consisting of three chiral DNS‐amino acids could be separated within 3.3 s utilizing a separation length of only 7 mm and an electrical field strength of 2012 V/cm." @default.
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• W1978577159 date "2004-11-01" @default.
• W1978577159 modified "2023-10-14" @default.
• W1978577159 title "Subsecond chiral separations on a microchip" @default.
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• W1978577159 doi "https://doi.org/10.1002/elps.200406028" @default.
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