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- W1978587960 abstract "Under the conditions of the benzilic acid rearrangement diaryl und dialkyl 1,2,3-triketones RCOCOCOR′ show two reactions: (1) Migration of RCO towards the more electronegative or less hindered CO group, yielding an α-hydroxy-β-ketoacid which can undergo secondary reactions, and (2) direct cleavage between adjacent carbonyl groups forming RCOOH and R′CHOHCOOH, RCO being more electronegative or less hindered than R′CO. The balance between these reactions depends upon the steric and electronic properties of R and R′." @default.
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- W1978587960 date "1974-11-06" @default.
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- W1978587960 title "Alkalische Spaltung und Benzilsäureumlagerung von 1,2,3-Triketonen. 29. Mitt. über Reduktone und Tricarbonylverbindungen [1]" @default.
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- W1978587960 doi "https://doi.org/10.1002/hlca.19740570738" @default.
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