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• W1978590602 abstract "Abstract Three new complexes, [Ni(deten) 2 Pd(μ-CN) 2 (CN) 2 ] n ( 1 ), [Zn(deten) 2 Pd(μ-CN) 2 (CN) 2 ] n ( 2 ) and [Cd(deten) 2 Pd(μ-CN) 2 (CN) 2 ] n ( 3 ) (deten = N,N-diethylethylenediamine), have been synthesized and characterized by elemental, spectral (FT-IR and Raman) and thermal analysis techniques. The crystal structures of the complexes 2 and 3 have been determined by X-ray single crystal diffraction. The crystallographic analysis reveals that they crystallize in the monoclinic system, space group P 2 1 /c. The Pd(II) atom is coordinated by four cyano groups. The M(II) atom is also surrounded by the two symmetry related deten ligands and the two symmetry related N atom of cyano groups. A possible decomposition of the complexes was investigated in the temperature range 30–700 °C in static air." @default.
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• W1978590602 date "2014-02-01" @default.
• W1978590602 modified "2023-09-22" @default.
• W1978590602 title "One-dimensional heteropolynuclear tetracyanopalladate(II) complexes: Syntheses, crystal structures, thermal analyses and spectroscopic investigations" @default.
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• W1978590602 doi "https://doi.org/10.1016/j.molstruc.2013.11.006" @default.
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