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- W1978593979 abstract "Abstract Core-shell copolymer emulsion of P(St + AA)/P(MMA + BA +DMAM) with solids content up to 60% was synthesized by the semi-continuous seed emulsion polymerization in which the pre-emulsified monomers were added dropwise. The effects of polymerization technique, the contents of seed emulsion, the amounts of emulsifier, the concentration of initiator, solid content, and polymerization temperature on emulsion particle size and its distribution were investigated. The emulsion particle morphology was characterized by transmission electron microscopy (TEM). The results indicated that the average particle size was within 200–600 nm and the particle size distribution index within 1.2–1.4. The particle size displays multidispersity. Keywords: Core-shell polymersEmulsion polymerizationHigh solid contentParticle size ACKNOWLEDGMENTS The Project Supported by the key Basic Research Program of Applied Basic Research Plan in Hebei Province of China (Program No. 09965121D). Notes Solid content: 60 wt%, initiator: 0.3 g/100 g monomers, Surfactant: 3 g/100 g monomers, surfactant wt. ratios: SDS/OP-10(w/w): 1/4, polymerization temperature: 80°C, shell monomer wt. ratios: MMA/BA/DMAM = 60/38/2. Solid content: 60 wt%, initiator: 0.3 g/100 g monomers, surfactant wt. ratios: SDBS/OP-10(w/w): 1/4, polymerization temperature: 80°C, shell monomer wt. ratios: MMA/BA/DMAM = 60/38/2. Solid content: 60 wt%, initiator: 0.3 g/100 g monomers, Surfactant: 3 g/100 g monomers, polymerization temperature: 80°C, shell monomer wt. ratios: MMA/BA/DMAM = 60/38/2. Solid content: 60 wt%, surfactant: 3.0 g/100 g monomer, surfactant wt. ratios: SDBS/OP-10(w/w): 1/4, polymerization temperature: 80°C, shell monomer wt. ratios: MMA/BA/DMAM = 60/38/2. Initiator: 0.3 g/100 g monomers, surfactant: 3.0 g/100 g monomer, surfactant wt. ratios: SDBS/OP-10(w/w): 1/4, polymerization temperature: 80°C, shell monomer wt. ratios: MMA/BA/DMAM = 60/38/2. Solid content: 60 wt%, initiator: 0.3 g/100 g monomers, surfactant: 3.0 g/100 g monomer, surfactant wt. ratios: SDBS/OP-10(w/w): 1/4, polymerization temperature: 80°C. Solid content: 60 wt%, initiator: 0.3 g/100 g monomers, Surfactant: 3 g/100 g monomers, surfactant wt. ratios: SDBS/OP-10(w/w): 1/4, shell monomer wt. ratios: MMA/BA/DMAM = 60/38/2." @default.
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- W1978593979 date "2011-02-17" @default.
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- W1978593979 title "Preparation of High Solid Content Emulsion with Core-Shell Structure" @default.
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- W1978593979 doi "https://doi.org/10.1080/03602559.2010.543226" @default.
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