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- W1978604815 abstract "In the oxidation of thiophenoxide and para-substituted thiophenoxide ions, the use of second-harmonic ac voltammetry at 25 Hz does not convert reactions that appear chemically irreversible in cyclic voltammetry into reversible systems as implied in previous publications. The reasons for these misinterpretations are unraveled. In spite of a fast dimerization reaction, with a rate constant ranging from 2×10 8 to 2×10 10 M -1 s -1 , the use of cyclic voltammetry at micro- and ultramicroelectrodes in appropriate ranges of concentration and scan rate allows the determination of the formal potentials of the ArS . /ArS - couple with a reasonable accuracy (from 5 to 30 mV)" @default.
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- W1978604815 date "1993-08-01" @default.
- W1978604815 modified "2023-09-26" @default.
- W1978604815 title "Determination of formal potentials of chemically unstable redox couples by second-harmonic alternating current voltammetry and cyclic voltammetry. Application to the oxidation of thiophenoxide ions" @default.
- W1978604815 doi "https://doi.org/10.1021/ja00070a026" @default.
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