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- W1978607312 abstract "Closed-shell interactions between the rare gases He, Ne, Ar, Kr, and Xe and the Ba2+ dication (isoelectronic with Xe) have been explored both experimentally and computationally. Unprecedented observations are reported for the formation of the diatomic molecules BaHe2+, BaAr2+, BaKr2+, and BaXe2+ in helium bath gas at room temperature in a selected ion flow tube (SIFT) tandem mass spectrometer. The Ba2+ dications were produced by electrospray ionization. Triatomic cations of the type Ba(Rg)22+ also were recorded with Rg = Ar, Kr, and Xe. Experiment and theory demonstrate that the rate of formation of BaRg2+ and the strength of the interaction between Rg and Ba2+ increase with increasing polarizability of the rare gas atom." @default.
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- W1978607312 date "2009-11-05" @default.
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- W1978607312 title "Strong Closed-Shell Interactions: Observed Formation of BaRg<sup>2+</sup> Molecules in the Gas Phase at Room Temperature" @default.
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- W1978607312 doi "https://doi.org/10.1021/jz900009q" @default.
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