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• W1978646407 abstract "Inverse gas chromatography has been used to measure the thermodynamic interaction between poly(4-hydroxystyrene) (P4HS) and poly(ε-caprolactone) (PCL) at 190°C. The retention behaviour of the homopolymers and three blends (0.25, 0.5 and 0.75 P4HS volume fraction) was characterized for 13 probes. The polymer-polymer interaction parameter χ23 calculated from the Soctt-Flory-Huggins formalism showed an apparent dependence on the probes. The method based on the equation-of-state theory given by Horta et al. and a more simplified method recently proposed by Deshpande were applied to eliminate the influence of the probe on χ23. The results of these methods were closely similar to the one obtained by melting-point depression of the PCL in the binary blends. Negative values of χ23 confirm the miscibility of the system. A blend composition dependence of χ23 has been found, leading to more miscible blends when the PCL content increases. This behaviour was related to the differences in the surface-to-volume ratio of both polymers." @default.
• W1978646407 created "2016-06-24" @default.
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• W1978646407 date "1995-01-01" @default.
• W1978646407 modified "2023-10-10" @default.
• W1978646407 title "Characterization of the interactions in the poly(4-hydroxystyrene)/ poly(?-caprolactone) system by inverse gas chromatography" @default.
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• W1978646407 doi "https://doi.org/10.1016/0032-3861(95)91566-p" @default.
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