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- W1978655413 abstract "The polyelectrolyte expansion of selected fractions of sodium lignin sulfonate has been measured viscometrically and by light scattering. Isoionic dilution techniques were used. The light-scattering radius of gyration, S̄, and the intrinsic viscosity, [η], increased with decrease in ionic strength IE and with S̄ proportional to [η]18. These results supported a microgel model for the macromolecule. The increase of [η] with decrease in IE was not in quantitative accord with the theories of Flory or with those of Hermans and Overbeek. A new theory was developed in which the molecule was assumed to have free charges only on the surface. The elastic energy of the expanding network was equated to the electrostatic energy in the double layer. The resulting equation was found to apply to the first part of the expansion, but at very low values of IE the expansion was less than predicted theoretically." @default.
- W1978655413 created "2016-06-24" @default.
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- W1978655413 date "1960-10-01" @default.
- W1978655413 modified "2023-10-15" @default.
- W1978655413 title "Polyelectrolyte expansion of a lignin sulfonate microgel" @default.
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- W1978655413 doi "https://doi.org/10.1016/0095-8522(60)90049-0" @default.
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