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- W1978664403 abstract "The features of the atomistic segregation-charge transfer (SCT) model needed to explain phase nucleation in binary alloy films, bombarded under conditions such that dense collision cascades develop, are outlined. A non-equilibrium compositional profile evolves at each cascade–matrix interface, due to segregation at the interface of one of the film components. Such a local stoichiometry change is associated with the development of an electronic density profile, which can be non-equilibrium over the typical timescale for cascade quenching. Relaxation to (meta)stable equilibrium occurs via charge transfer reactions, which give rise to the formation of dimers of an effective compound. The amount of energy required to introduce an effective alloy dimer into the matrix is calculated and the surface and thermochemical properties of the initial and effective alloys are compared. The model is applied to the analysis of 21 alloys, out of which 10 were amorphized by ion beams, and qualitative differences are found between the systems undergoing amorphization and crystalline phase formation." @default.
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- W1978664403 date "1998-07-01" @default.
- W1978664403 modified "2023-09-26" @default.
- W1978664403 title "Vitrification processes under energetic ion bombardment" @default.
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- W1978664403 doi "https://doi.org/10.1016/s0022-3093(98)00383-4" @default.
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