FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978676945> ?p ?o ?g. }

• W1978676945 endingPage "3092" @default.
• W1978676945 startingPage "3083" @default.
• W1978676945 abstract "Abstract In this paper, possible sources for the unexpected distributions of crystalline sequence lengths calculated from temperature rising elution fractionation (TREF) calibration experiments, as reported in a previous work, are investigated. With this aim, chain folding and cocrystalization phenomena were explored in the conditions of crystallization as used for TREF or crystallization analysis fractionation (CRYSTAF). Slow crystallizations were performed from xylene solutions of model low molecular weight ethylene homopolymers with narrow molecular weight distributions. The same experiments were performed with homopolymers having narrow molecular weight distributions and with blends having wide molecular weight distributions. The resulting distributions of the lengths of crystalline methylene sequences were directly studied by Raman in the so‐called longitudinal acoustic mode (LAM) and by DSC. For ethylene homopolymers with molecular weights below 2000 g/mol, the results from Raman LAM indicate that slow crystallization in TREF or CRYSTAF systems occurs in the extended‐chain mode. For higher molecular weights, evidence of chain folding was found. In the case of blends, independent crystallization was observed for each molecular weight when the molecular weight ranges used for the blends are relatively narrow. Cocrystallization was observed when this range was increased. Overall, these results strongly support the inverse technique calculation procedure developed by our group for the calculation of distributions of lengths of crystallizable sequences from TREF spectra. In this context, the results confirm that the unexpected crystallizable sequence lengths found in our previous work really exist and can be associated to chain folding or cocrystallization phenomena. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 3083–3092, 2005" @default.
• W1978676945 created "2016-06-24" @default.
• W1978676945 creator A5028758588 @default.
• W1978676945 creator A5046287405 @default.
• W1978676945 creator A5081765632 @default.
• W1978676945 date "2005-09-21" @default.
• W1978676945 modified "2023-10-10" @default.
• W1978676945 title "Fractionation process in TREF systems: Validation of thermodynamic model and calculation procedure by Raman LAM studies" @default.
• W1978676945 cites W1964447020 @default.
• W1978676945 cites W1965523041 @default.
• W1978676945 cites W1965853609 @default.
• W1978676945 cites W1967623307 @default.
• W1978676945 cites W1969596469 @default.
• W1978676945 cites W1972306719 @default.
• W1978676945 cites W1988346130 @default.
• W1978676945 cites W1990967987 @default.
• W1978676945 cites W1995839367 @default.
• W1978676945 cites W2008502573 @default.
• W1978676945 cites W2011009223 @default.
• W1978676945 cites W2011077294 @default.
• W1978676945 cites W2012284153 @default.
• W1978676945 cites W2013369066 @default.
• W1978676945 cites W2025222159 @default.
• W1978676945 cites W2032907897 @default.
• W1978676945 cites W2035098540 @default.
• W1978676945 cites W2044454377 @default.
• W1978676945 cites W2047052681 @default.
• W1978676945 cites W2056369366 @default.
• W1978676945 cites W2080583197 @default.
• W1978676945 cites W2084018809 @default.
• W1978676945 cites W2107314232 @default.
• W1978676945 cites W2107675005 @default.
• W1978676945 cites W2163078692 @default.
• W1978676945 cites W2950665075 @default.
• W1978676945 doi "https://doi.org/10.1002/polb.20582" @default.
• W1978676945 hasPublicationYear "2005" @default.
• W1978676945 type Work @default.
• W1978676945 sameAs 1978676945 @default.
• W1978676945 citedByCount "7" @default.
• W1978676945 countsByYear W19786769452012 @default.
• W1978676945 countsByYear W19786769452014 @default.
• W1978676945 countsByYear W19786769452018 @default.
• W1978676945 countsByYear W19786769452020 @default.
• W1978676945 countsByYear W19786769452021 @default.
• W1978676945 crossrefType "journal-article" @default.
• W1978676945 hasAuthorship W1978676945A5028758588 @default.
• W1978676945 hasAuthorship W1978676945A5046287405 @default.
• W1978676945 hasAuthorship W1978676945A5081765632 @default.
• W1978676945 hasConcept C113196181 @default.
• W1978676945 hasConcept C120665830 @default.
• W1978676945 hasConcept C121332964 @default.
• W1978676945 hasConcept C147597530 @default.
• W1978676945 hasConcept C151730666 @default.
• W1978676945 hasConcept C158117686 @default.
• W1978676945 hasConcept C178790620 @default.
• W1978676945 hasConcept C185592680 @default.
• W1978676945 hasConcept C18762648 @default.
• W1978676945 hasConcept C192562407 @default.
• W1978676945 hasConcept C203036418 @default.
• W1978676945 hasConcept C2779343474 @default.
• W1978676945 hasConcept C40003534 @default.
• W1978676945 hasConcept C43617362 @default.
• W1978676945 hasConcept C521977710 @default.
• W1978676945 hasConcept C59593255 @default.
• W1978676945 hasConcept C86803240 @default.
• W1978676945 hasConcept C97355855 @default.
• W1978676945 hasConcept C97428945 @default.
• W1978676945 hasConceptScore W1978676945C113196181 @default.
• W1978676945 hasConceptScore W1978676945C120665830 @default.
• W1978676945 hasConceptScore W1978676945C121332964 @default.
• W1978676945 hasConceptScore W1978676945C147597530 @default.
• W1978676945 hasConceptScore W1978676945C151730666 @default.
• W1978676945 hasConceptScore W1978676945C158117686 @default.
• W1978676945 hasConceptScore W1978676945C178790620 @default.
• W1978676945 hasConceptScore W1978676945C185592680 @default.
• W1978676945 hasConceptScore W1978676945C18762648 @default.
• W1978676945 hasConceptScore W1978676945C192562407 @default.
• W1978676945 hasConceptScore W1978676945C203036418 @default.
• W1978676945 hasConceptScore W1978676945C2779343474 @default.
• W1978676945 hasConceptScore W1978676945C40003534 @default.
• W1978676945 hasConceptScore W1978676945C43617362 @default.
• W1978676945 hasConceptScore W1978676945C521977710 @default.
• W1978676945 hasConceptScore W1978676945C59593255 @default.
• W1978676945 hasConceptScore W1978676945C86803240 @default.
• W1978676945 hasConceptScore W1978676945C97355855 @default.
• W1978676945 hasConceptScore W1978676945C97428945 @default.
• W1978676945 hasIssue "21" @default.
• W1978676945 hasLocation W19786769451 @default.
• W1978676945 hasOpenAccess W1978676945 @default.
• W1978676945 hasPrimaryLocation W19786769451 @default.
• W1978676945 hasRelatedWork W1975066220 @default.
• W1978676945 hasRelatedWork W1975083980 @default.
• W1978676945 hasRelatedWork W2056352805 @default.
• W1978676945 hasRelatedWork W2058864804 @default.
• W1978676945 hasRelatedWork W2075298763 @default.
• W1978676945 hasRelatedWork W2148403720 @default.
• W1978676945 hasRelatedWork W2361648762 @default.
• W1978676945 hasRelatedWork W2385571654 @default.

• next