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- W1978678493 abstract "The dynamics of the scattering of nitric oxide (NO) from well-characterized and ordered layers of carbon monoxide (CO) and ethylidyne (CCH3) adsorbed on a Pt(111) substrate have been investigated through resonance-enhanced multiphoton ionization (REMPI) measurements of the rotational quantum state distributions of the scattered NO molecules for a range of incident NO translational energies between 10 and 50 kJ mol−1 from scattering substrates at 108 and 300 K. The measurements reveal that, where in principle the interaction potential resembles that of the NO–Ag(111) system more so than that of the NO–Pt(111) system, the scattering differs remarkably from that expected from a weakly bound system in that it occurs both into a trapping-desorption channel and a direct inelastic channel. Experimental data are presented that indicate both an incident translational energy dependence and substrate surface temperature dependence of the scattering, which is interpreted in terms of a hard-cube model." @default.
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- W1978678493 date "2000-11-15" @default.
- W1978678493 modified "2023-09-26" @default.
- W1978678493 title "Energy disposal in collisions of nitric oxide with molecular adlayers on transition metal single crystal surfaces: Rotational energy disposal" @default.
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- W1978678493 doi "https://doi.org/10.1063/1.1318198" @default.
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