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- W1978687629 abstract "Abstract The equilibration kinetics of single‐crystal TiO 2 were determined in the rapid kinetics regime (within the first 10 h) within narrow ranges of oxygen activities, p (O 2 ), under the conditions of 1198–1323 K and p (O 2 ) = 10 –10 –10 5 Pa. The determined chemical diffusion coefficient, D chem , is observed to exhibit a complex dependence on p (O 2 ). Comparison of D chem for single‐crystal and polycrystalline TiO 2 demonstrates that the grain boundaries have a retarding effect on the transport of defects. The present work represents the first assessment of the effect of nonstoichiometry on well defined D chem for TiO 2 within a wide range of p (O 2 ). (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)" @default.
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- W1978687629 date "2005-08-02" @default.
- W1978687629 modified "2023-10-17" @default.
- W1978687629 title "Equilibration kinetics of TiO<sub>2</sub> single crystal at elevated temperatures" @default.
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- W1978687629 doi "https://doi.org/10.1002/pssb.200541187" @default.
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