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- W1978689682 abstract "The behaviour of Yb(III-II) and Sm(III-II) couples has been investigated in AlCl3+1-n-butylpyridinium chloride (BPC) mixtures at 40°C, by voltammetric and spectrophotometric methods. In very acidic melts, the two trivalent lanthanides can be reduced reversibly and solutions of divalent oxidation states are stable. The E1/2 potentials measured with respect to an Al electrode dipping in a melt containing 57 mol% of AlCl3 are constant and located respectively at +1.230 V (Yb) and +0.660 V (Sm). If the acidity of the melt is decreased, the lanthanide cations precipitate and the half-wave potentials exhibit a cathodic shift. These phenomena are explained in terms of cationic chlorocomplexes, depending on the pCl, the oxidation state and the atomic number. Species such as YbCl2+, YbCl+ and SmCl2+, Sm3+, Sm2+ are proposed." @default.
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- W1978689682 date "1976-01-01" @default.
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- W1978689682 title "Electrochemical studies on the existence of divalent oxidation states of selected actinides in acetonitrile solution" @default.
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- W1978689682 doi "https://doi.org/10.1016/0020-1650(76)80153-5" @default.
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