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- W1978699767 abstract "Abstract The absorption spectrum of the vapour of CF 2 ClBr (BCF) was measured over a wide range of pressures. Absorption cross sections in the range 190 – 340 nm are given. BCF vapour was photolysed at 248 nm and 20 °C, alone and with each of the radical scavengers HCl, HBr, Cl 2 and Br 2 . Quantum yields of the products were measured. Two primary modes of photodecomposition are proposed: The mechanism of the photolysis is discussed. Irradiation of BCF at 313 nm gave no detectable products with φ(−BCF) ⩽ 0.01. However, BCF vapour is readily photodecomposed at 313 nm if liquid mercury is present. Results of the long-term exposure of BCF vapour to sunshine (up to 3 years) under various conditions are described." @default.
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- W1978699767 date "1982-01-01" @default.
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- W1978699767 title "UV absorption spectrum and photochemistry of CF2ClBr" @default.
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- W1978699767 doi "https://doi.org/10.1016/0047-2670(82)80031-2" @default.
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