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• W1978713033 abstract "Self-assembly of block copolymers confined in cylindrical nanopores is studied systematically using a simulated annealing technique. For diblock copolymers which form two-dimensional hexagonally packed cylinders with period L0 in the bulk, novel structures such as helices and stacked toroids spontaneously form inside the cylindrical pores. These confinement-induced morphologies have no counterpart in the bulk system and they depend on the pore diameter (D) and the surface-polymer interactions, reflecting the importance of structural frustration and interfacial interactions. On tightening the degree of confinement, transitions from helices to toroids to spheres are observed. Mechanisms of the morphological transitions can be understood based on the degree of structural frustration parametrized by the ratio D/L0." @default.
• W1978713033 created "2016-06-24" @default.
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• W1978713033 date "2006-04-06" @default.
• W1978713033 modified "2023-10-18" @default.
• W1978713033 title "Confinement-Induced Novel Morphologies of Block Copolymers" @default.
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• W1978713033 doi "https://doi.org/10.1103/physrevlett.96.138306" @default.
• W1978713033 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16712046" @default.
• W1978713033 hasPublicationYear "2006" @default.
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