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- W1978713902 abstract "Resonance Raman spectra of 15N enriched metallooctaethylporphyrins [M(OEP) − 15N4] [M = Ni2+, Fe3+ (high spin), and Fe3+ (low spin)] were observed. Polarized Raman lines corresponding to the oxidation state marker band of hemoproteins were observed at 1377 (Ni), 1369 (Fe high spin) and 1372−1 (Fe low spin) which were shifted to lower frequency from those of the 14N compounds by 6, 5, and 6 cm−1, respectively. The vibrational mode for this band was shown to include an appreciable contribution of the CαN symmetric stretching vibration and to be associated with ca. 0.01 Å of in-phase displacement of the four pyrrole nitrogens toward the metal ion." @default.
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- W1978713902 date "1977-05-01" @default.
- W1978713902 modified "2023-10-06" @default.
- W1978713902 title "Resonance Raman spectra of 15N enriched metallooctaethylorphyrins. Characterization of the oxidation state marker bands of hemoproteins" @default.
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- W1978713902 doi "https://doi.org/10.1016/0009-2614(77)80212-1" @default.
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