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• W1978714581 abstract "A kind of promising hydrogen storage material-hydrazine bisborane (N2H4(BH3)2, HBB) is synthesized by a typical chemical method. HBB exhibits relatively low dehydrogenation temperature (around 100 °C), effective prevention of any unwanted gaseous products, such as ammonia, diborane, confirming a very high hydrogen release purity of >99%. The activation energy (Ea) of the first-step dehydrogenation of HBB is calculated to be 106.4 kJ/mol using Kissinger’s method. According to the 11B NMR and FT-IR results, the thermal decomposition of HBB was determined to produce [HBN2BH]2 dimers, in which the coordination environment of B atoms located in the formation of HBN2." @default.
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• W1978714581 date "2011-10-01" @default.
• W1978714581 modified "2023-09-24" @default.
• W1978714581 title "Hydrazine bisborane as a promising material for chemical hydrogen storage" @default.
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• W1978714581 doi "https://doi.org/10.1016/j.ijhydene.2011.07.104" @default.
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