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• W1978729194 abstract "Transformation of reactive isochromenylium intermediates to the corresponding storable and stable reagents has been achieved, and a number of isochromenylium tetrafluoroborates (ICTBs, 1) have been conveniently prepared and characterized. Direct metal-free treatment of isochromenylium tetrafluoroborate 1a with olefins afforded a variety of polycyclic frameworks 4 via mild cascade reactions. Starting from the prefunctionalized o-alkynylbenzaldehydes, a one-pot metal-free procedure of intramolecular cascade annulation to 2,3-dihydrophenanthren-4(1H)-one derivatives was also developed." @default.
• W1978729194 created "2016-06-24" @default.
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• W1978729194 date "2009-09-18" @default.
• W1978729194 modified "2023-09-27" @default.
• W1978729194 title "Transformation of Reactive Isochromenylium Intermediates to Stable Salts and Their Cascade Reactions with Olefins" @default.
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• W1978729194 doi "https://doi.org/10.1021/ol9019524" @default.
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