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- W1978729237 abstract "The reactions with a variety of monodentate Lewis bases (L) of (bidentate)M(CO)4 (M = Cr, Mo) complexes in which the bidentate ligand contains amine, phosphine or sulfide functional groups have been investigated. For (DTH)Cr(CO)4 (DTH = 2,5-dithiahexane), (DTH)Mo(CO)4, (tmen)Cr(CO)4, (tmen)Cr(CO)4 (tmen = N,N,N',N' tetramethylethylenediamine), (NP)Cr(CO)4 (NP=1(diethylamino)-2-(diphenylphosphino)-ethane)and (NP)Mo(CO)4, replacement of the bidentate ligand was observed, with the formation of cis or trans-(L)2M(CO)4 or cis-(L)3M(CO)3 products, depending upon the L ligand employed. Several new complexes have been prepared through use of this route. The reaction of (tmen)Mo(CO)4 with L involves two competitive processes, either replacement of tmen, or the replacement of CO to form a «mixed» derivative, cis-(L)(tmen)Mo(CO)3, followed by replacement of tmen. The partition of the reaction between the two paths is dependent upon the steric nature of L. Reactions of (diphos)-Mo(CO)4 = 1,2-bis(diphenylphosphino)ethane) with L give «mixed»derivatives of the types cis and trans(L)(diphos)Mo(CO)3andcis(L)2(diphos)Mo(CO)2, the extent of carbonyl replacement and product stereochemistry again being a function of the ligand employed. The results, together with other data cited from the literature may best be explained in terms of σ as well as π-bonding effects in octahedral metal carbonyl systems." @default.
- W1978729237 created "2016-06-24" @default.
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- W1978729237 date "1967-01-01" @default.
- W1978729237 modified "2023-10-16" @default.
- W1978729237 title "Octahedral metal carbonyls: Reactions and bonding. VI Derivatives of some octahedral metal carbonyl complexes containing bidentate ligands" @default.
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- W1978729237 doi "https://doi.org/10.1016/s0020-1693(00)93188-8" @default.
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