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- W1978736073 abstract "Accurate measurements are reported of the equation of state of ethene on 16 isochores within ± 40 per cent of the critical density and at temperatures from 220 to 303 K. Two samples, one of 99.993 and one of 99.999 moles per cent C2H4, have been used. The principal source of experimental error is found to be impurity. A model for predicting the effect of knwwn small impurities is developed and used to explain qualitatively the observed differences between the results for our two samples as well as those between our own and other recently-reported accurate measurements. A scaled fundamental equation, incorporating Ising-like asymptotic behavior, revisions of and corrections to scaling, has been fitted to the results for the 99.993 moles per cent pure sample. The equation, with nine adjustable parameters, represents the measured values to within an estimated uncertainty of 5 × 10−4 K in temperature, 5 × 10−5 MPa in pressure, and 0.003 mol dm−3 in amount-of-substance density. The criticalpoint parameters resulting from the fit are presented. Comparisons are made with two other sets of measurements recently published. The agreement is generally satisfactory." @default.
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- W1978736073 date "1980-11-01" @default.
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- W1978736073 title "The critical-region equation of state of ethene and the effect of small impurities" @default.
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- W1978736073 doi "https://doi.org/10.1016/0021-9614(80)90158-5" @default.
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